A kinetic model for the degradation of benzothiazole by Fe3+-photo-assisted Fenton process in a completely mixed batch reactor

被引：39

作者：

Andreozzi, R ^{[1
]}

D'Apuzzo, A ^{[1
]}

Marotta, R ^{[1
]}

机构：

[1] Univ Naples Federico II, Fac Ingn, Dipartimento Ingn Chim, I-80125 Naples, Italy

来源：

JOURNAL OF HAZARDOUS MATERIALS | 2000年 / 80卷 / 1-3期

关键词：

benzothiazoles; advanced oxidation process; photo-Fenton system; kinetic model; hydrogen peroxide; hydroxyl radical; ferric ion; wastewater treatment;

D O I：

10.1016/S0304-3894(00)00308-3

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

The degradation of benzothiazole in aqueous solution by a photo-assisted Fenton reaction has been studied in a batch reactor in the pH range 2.0-3.2 and for H2O2 and Fe(III) concentrations respectively between 1.0 x 10(-3)-1.5 x 10(-1) and 1.0 x 10(-6)-4.0 x 10(-6) M. A kinetic model has been developed to predict the decay of benzothiazole at varying reaction conditions. The use of kinetic constants from the literature in the model allows to simulate the system behavior by taking into account the influence of pH, hydrogen peroxide, Fe(III) and sulfate concentrations and the ionic strength. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：241 / 257

页数：17

共 51 条

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ANDREOZZI R, 2000, UNPUB WATER RES

[2]

[Anonymous], 1983, ENG OPTIMIZATION

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