Pyrazole and benzothiazole palladacycles: stable and efficient catalysts for carbon-carbon bond formation

被引：92

作者：

Gai, XJ

Grigg, R ^{[1
]}

Ramzan, MI

Sridharan, V

Collard, S

Muir, JE

机构：

[1] Univ Leeds, Sch Chem, Mol Innovat Divers & Automated Synth Ctr, Leeds LS2 9JT, W Yorkshire, England

[2] Johnson Matthey, Royston SG8 5HE, Herts, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 20期

关键词：

D O I：

10.1039/b005452f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclopalladated phosphine free pyrazole complexes 1 and benzothiazole complexes 2 are excellent catalysts for the Heck vinylation of aryl iodides and termolecular queuing cascades, leading to turnover numbers of > 10(6) in some cases, at moderate temperatures; these catalysts show high thermal stability and are not sensitive to moisture and air.

引用

页码：2053 / 2054

页数：2

共 22 条

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