Photoabsorption spectrum of ozone in the K-edge region

被引：15

作者：

Gejo, T

Okada, K

Ibuki, T

机构：

[1] Institute for Molecular Science, Myodaiji

[2] Department of Chemistry, Faculty of Science, Hiroshima University

[3] Kyoto University of Education, Kyoto 612, Fukakusa, Fushimi-ku

来源：

CHEMICAL PHYSICS LETTERS | 1997年 / 277卷 / 5-6期

关键词：

D O I：

10.1016/S0009-2614(97)00965-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The K-shell (1s) photoabsorption spectrum of ozone has been studied for the first time by using synchrotron radiation as a light source. The total photoabsorption cross section exhibits two distinct leaks at 529.1 and 535.4 eV attributed to the pi* <-- O(1s) transitions of the terminal and the central oxygen atoms in ozone, respectively. The sigma* <-- O(1s) transition bands were also observed. (C) 1997 Published by Elsevier Science B.V.

引用

收藏

页码：497 / 501

页数：5

相关论文

共 19 条

[1] RENNER-TELLER EFFECT AND RYDBERG-VALENCE MIXING IN THE N AND O K-EDGE PHOTOABSORPTION SPECTRA OF N2O [J].

ADACHI, JI ;

KOSUGI, N .

JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (19) :7369-7376

[2] STUDY OF CORE ELECTRON-BINDING ENERGIES OF OZONE BY X-RAY PHOTOELECTRON-SPECTROSCOPY AND X-ALPHA SCATTERED WAVE METHOD [J].

BANNA, MS ;

FROST, DC ;

MCDOWELL, CA ;

NOODLEMAN, L ;

WALLBANK, B .

CHEMICAL PHYSICS LETTERS, 1977, 49 (02) :213-217

[3] VACUUM ULTRAVIOLET PHOTOELECTRON-SPECTROSCOPY OF TRANSIENT SPECIES .4. DIFLUOROMETHYLENE AND OZONE [J].

DYKE, JM ;

GOLOB, L ;

JONATHAN, N ;

MORREIS, A ;

OKUDA, M .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1974, 70 :1828-1836

[4]

HEY PJ, 1975, J CHEM PHYS, V62, P3912

[5] CONSTRUCTION OF CONSTANT-DEVIATION CONSTANT-LENGTH SPHERICAL GRATING MONOCHROMATOR AT UVSOR [J].

HIRAYA, A ;

NAKAMURA, E ;

HASUMOTO, M ;

KINOSHITA, T ;

SAKAI, K ;

ISHIGURO, E ;

WATANABE, M .

REVIEW OF SCIENTIFIC INSTRUMENTS, 1995, 66 (02) :2104-2106

[6]

HITCHCOCK AP, COREX DATABASE

[7]

HITCHCOCK AP, 1994, BIBLIOGRAPHY ATOMIC

[8]

Huzinaga S., 1984, Gaussian Basis Sets for Molecular Calculations

[9] PHOTOELECTRON ANGULAR-DISTRIBUTION AND ASSIGNMENT OF PHOTOELECTRON-SPECTRUM OF OZONE [J].

KATSUMATA, S ;

SHIROMARU, H ;

KIMURA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (07) :1784-1788

[10] EFFICIENT METHODS FOR SOLVING THE OPEN-SHELL SCF PROBLEM AND FOR OBTAINING AN INITIAL GUESS - THE ONE-HAMILTONIAN AND THE PARTIAL SCF METHODS [J].

KOSUGI, N ;

KURODA, H .

CHEMICAL PHYSICS LETTERS, 1980, 74 (03) :490-493