1,4-anti induction in C-glycosylation of pentose glycals

被引：66

作者：

Hosokawa, S ^{[1
]}

Kirschbaum, B ^{[1
]}

Isobe, M ^{[1
]}

机构：

[1] Nagoya Univ, Sch Bioagr Sci, Organ Chem Lab, Chikusa Ku, Nagoya, Aichi 46401, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(98)00047-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The C-glycosylation of pentose glycals with silylacetylenes or allylsilanes via oxocarbenium ion intermediates proceeded under high regio-and stereoselectivity giving the 1,4-anti products as the predominant products. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1917 / 1920

页数：4

共 19 条

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