Industrial Oxidations with Organocatalyst TEMPO and Its Derivatives

被引：309

作者：

Ciriminna, Rosaria ^{[1
]}

Pagliaro, Mario ^{[1
]}

机构：

[1] CNR, Ist Studio Mat Nanostrutturati, I-90146 Palermo, Italy

来源：

ORGANIC PROCESS RESEARCH & DEVELOPMENT | 2010年 / 14卷 / 01期

关键词：

PRIMARY ALCOHOLS; CATALYZED OXIDATION; SELECTIVE OXIDATION; SECONDARY ALCOHOLS; AEROBIC OXIDATION; ALDEHYDES; KETONES; ACIDS;

D O I：

10.1021/op900059x

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The radical TEMPO and its derivatives find a variety of industrial applications as highly selective oxidation catalysts for the production of pharmaceuticals, flavors and fragrances, agrochemicals, and a variety of other specialty chemicals. Reviewing recent notable examples, we show how and why homogeneous and heterogeneous TEMPO-mediated oxidations are becoming part of a central toolbox in industrial organic synthesis applicable for the conversion of alcohols into aldehydes, ketones, and carboxylic acids.

引用

页码：245 / 251

页数：7

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