Solution thermochemical study of a fluorous tertiary phosphine ligand in rhodium and ruthenium systems

被引：21

作者：

Li, CB

Nolan, SP ^{[1
]}

Horvath, IT

机构：

[1] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

[2] Exxon Res & Engn Co, Corp Res Labs, Annandale, NJ 08801 USA

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 03期

关键词：

D O I：

10.1021/om970805o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The enthalpies of reaction of a fluorous tertiary phosphine, P(CH2CH2(CF2)(5)CF3)(3) (PRf3) with [Rh(CO)(2)Cl](2) (1) and Cp'Ru(COD)Cl (Cp' = eta(5)-C5H5 (2), eta(5)-C5Me5 (3)) leading to the formation of RhCl(CO)(PRf3)(2) and Cp'Ru(PRf3)(2)Cl complexes have been measured by anaerobic solution calorimetry in THF at 30.0 degrees C. These reactions are rapid and quantitative. The measured reaction enthalpies allow for a quantitative determination of characteristic phosphine steric and electronic parameters associated with this novel tertiary phosphine ligand. Sterically, the P(CH2CH2(CF2)(5)CF3)(3) ligand appears identical to PEt3.

引用

页码：452 / 456

页数：5

共 65 条

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