A simple but effective ferrocene derivative as a redox, colorimetric, and fluorescent receptor for highly selective recognition of Zn2+ ions

被引:83
作者
Zapata, Fabiola [1 ]
Caballero, Antonio [1 ]
Espinosa, Arturo [1 ]
Tarraga, Alberto [1 ]
Molina, Pedro [1 ]
机构
[1] Univ Murcia, Fac Quim, Dept Quim Organ, E-30100 Murcia, Spain
关键词
D O I
10.1021/ol070828r
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new probe, based on a 1,1 '-disubstituted ferrocene, senses Zn2+ selectively among heavy and transition-metal (HTM) ions through three different channels: anodic redox shift of the Fe(II)/Fe(III) redox couple, the orange to deep purple color change that is visible to the naked-eye, and a remarkable enhancement of the fluorescence.
引用
收藏
页码:2385 / 2388
页数:4
相关论文
共 51 条
[1]   A new fluorescent probe for zinc(II):: An 8-hydroxy-5-N,N-dimethylaminosulfonylquinoline-pendant 1,4,7,10-tetraazacyclododecane [J].
Aoki, Shin ;
Sakurama, Kazusa ;
Matsuo, Nanako ;
Yamada, Yasuyuki ;
Takasawa, Ryoko ;
Tanuma, Sei-ichi ;
Shiro, Motoo ;
Takeda, Kei ;
Kimura, Eiichi .
CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (35) :9066-9080
[2]   Copper, zinc, and the metallobiology of Alzheimer disease [J].
Bush, AI .
ALZHEIMER DISEASE & ASSOCIATED DISORDERS, 2003, 17 (03) :147-150
[3]   The metallobiology of Alzheimer's disease [J].
Bush, AI .
TRENDS IN NEUROSCIENCES, 2003, 26 (04) :207-214
[4]  
Caballero A, 2006, DALTON T, P1390, DOI 10.1039/b508757k
[5]   Highly selective chromogenic and redox or fluorescent sensors of Hg2+ in aqueous environment based on 1,4-disubstituted azines [J].
Caballero, A ;
Martínez, R ;
Lloveras, V ;
Ratera, I ;
Vidal-Gancedo, J ;
Wurst, K ;
Tárraga, A ;
Molina, P ;
Veciana, J .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (45) :15666-15667
[6]   Multifunctional linear triferrocene derivatives linked by oxidizable bridges:: Optical, electronic, and cation sensing properties [J].
Caballero, A ;
Tárraga, A ;
Velasco, MD ;
Espinosa, A ;
Molina, P .
ORGANIC LETTERS, 2005, 7 (15) :3171-3174
[7]   An electroactive nitrogen-rich [4.4]ferrocenophane displaying redox-switchable behavior:: Selective sensing, complexation, and decomplexation of Mg2+ ions [J].
Caballero, A ;
Lloveras, V ;
Tárraga, A ;
Espinosa, A ;
Velasco, MD ;
Vidal-Gancedo, J ;
Rovira, C ;
Wurst, K ;
Molina, P ;
Veciana, J .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (13) :1977-1981
[8]   Selective fluorescence sensing of Li+ in an aqueous environment by a ferrocene-anthracene-linked dyad [J].
Caballero, A ;
Tormos, R ;
Espinosa, A ;
Velasco, MD ;
Tárraga, A ;
Miranda, MA ;
Molina, P .
ORGANIC LETTERS, 2004, 6 (24) :4599-4602
[9]   Multifunctional ferrocene-ruthenocene dyads linked by single or double aza-containing bridges displaying metal-metal interactions and cation recognition properties [J].
Caballero, Antonio ;
Garcia, Rafaela ;
Espinosa, Arturo ;
Tarraga, Alberto ;
Molina, Pedro .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (04) :1161-1173
[10]   Electroactive thiazole derivatives capped with ferrocenyl units showing charge-transfer transition and selective ion-sensing properties:: A combined experimental and theoretical study [J].
Caballero, Antonio ;
Lloveras, Vega ;
Curiel, David ;
Tarraga, Alberto ;
Espinosa, Arturo ;
Garcia, Rafaela ;
Vidal-Gancedo, Jose ;
Rovira, Concepcio ;
Wurst, Klaus ;
Molina, Pedro ;
Veciana, Jaume .
INORGANIC CHEMISTRY, 2007, 46 (03) :825-838