Aggregation of ferrocene pendant groups along the backbone of DNA for a supramolecular redox system

被引：14

作者：

Hirao, T ^{[1
]}

Nomoto, A ^{[1
]}

Yamazaki, S ^{[1
]}

Ogawa, A ^{[1
]}

Moriuchi, T ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 565, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(98)00656-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Redox-active ferrocenes bearing a long alkylene chain (FUT) were aggregated along the backbone of double helical DNA to afford redox-active (outer) and hydrophobic (inner) spheres around the double helical core. In this system, the redox potential of the ferrocene moiety shifted anodically, compared with the uncomplexed FUT, possibly due to hydrophobic interaction between the long alkylene chains. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4295 / 4298

页数：4

共 19 条

[1] Peptide helix induction in a self-assembling hemoprotein model [J].

Arnold, PA ;

Shelton, WR ;

Benson, DR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (13) :3181-3182

[2]

BEER PD, 1996, J CHEM SOC CHEM COMM, P689

[3] Oxidative thymine dimer repair in the DNA helix [J].

Dandliker, PJ ;

Holmlin, RE ;

Barton, JK .

SCIENCE, 1997, 275 (5305) :1465-1468

[4] IONIC-CONDUCTIVITY INDUCED BY PHOTOOXIDATION OF FERROCENE IN POLYMER FILM CONTAINING ORGANOTIN COMPOUND [J].

FUJINAMI, T ;

KAWAHARA, N ;

SAKAI, S ;

OGITA, M .

CHEMISTRY LETTERS, 1993, (04) :585-588

[5] SYNTHESIS AND STRUCTURE OF (CIS)-[1-FERROCENYL-2-(4-NITROPHENYL)ETHYLENE], AN ORGANOTRANSITION METAL COMPOUND WITH A LARGE 2ND-ORDER OPTICAL NONLINEARITY [J].

GREEN, MLH ;

MARDER, SR ;

THOMPSON, ME ;

BANDY, JA ;

BLOOR, D ;

KOLINSKY, PV ;

JONES, RJ .

NATURE, 1987, 330 (6146) :360-362

[6] Photoinduced electron transfer along a beta-sheet mimic [J].

Gretchikhine, AB ;

Ogawa, MY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (06) :1543-1544

[7] Oxidative DNA damage through long-range electron transfer [J].

Hall, DB ;

Holmlin, RE ;

Barton, JK .

NATURE, 1996, 382 (6593) :731-735

[8] PREPARATION OF ORGANIC THIN-FILMS BY MICELLAR DISRUPTION METHOD UNDER VARIOUS ELECTROLYTIC AND SOLUTION CONDITIONS [J].

HOSHINO, K ;

SAJI, T .

NIPPON KAGAKU KAISHI, 1990, (10) :1014-1019

[9]

IHARA T, 1997, J CHEM SOC CHEM COMM, P1609

[10] Synthesis of a ferrocenyl-capped ruthenium(II) bis(acetylide) complex: A model for organometallic molecular wires [J].

Jones, ND ;

Wolf, MO ;

Giaquinta, DM .

ORGANOMETALLICS, 1997, 16 (07) :1352-1354

← 1 2 →