Raman investigation of the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide and its mixture with LiN(SO2CF3)2

被引：188

作者：

Castriota, M

Caruso, T

Agostino, RG

Cazzanelli, E

Henderson, WA

Passerini, S

机构：

[1] IDROCOMB, ENEA, Italian Agcy New Technol Energy & Environm, I-00060 Rome, Italy

[2] Univ Calabria, Dept Phys, LiCryl, INFM, I-87036 Arcavacata Di Rende, CS, Italy

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2005年 / 109卷 / 01期

关键词：

D O I：

10.1021/jp046030w

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A preliminary Raman investigation of the ionic liquid N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide (PYR13TFSI) and its 2/1 complex with the lithium salt LiN(SO2CF3)(2) is reported. The study was performed over a temperature range extending from -100 to +60 degreesC, i.e., with PYR13TFSI in the crystalline and melt states. For comparison purposes, the study was extended to PYR13I, which is the precursor used in the synthesis of PYR13TFSI.

引用

收藏

页码：92 / 96

页数：5

相关论文

共 26 条

[1] Clean and green ... but are they mean? [J].

Adam, D .

NATURE, 2000, 407 (6807) :938-940

[2] Ab initio calculations, Raman and NMR investigation of the plastic crystal di-methyl pyrrolidinium iodide [J].

Adebahr, J ;

Johansson, P ;

Jacobsson, P ;

MacFarlane, DR ;

Forsyth, M .

ELECTROCHIMICA ACTA, 2003, 48 (14-16) :2283-2289

[3] Characterizing ionic liquids on the basis of multiple solvation interactions [J].

Anderson, JL ;

Ding, J ;

Welton, T ;

Armstrong, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (47) :14247-14254

[4] CONTACT ION-PAIR FORMATION AND ETHER OXYGEN COORDINATION IN THE POLYMER ELECTROLYTES M[N(CF3SO2)(2)](2)PEO(N) FOR M=MG, CA, SR AND BA [J].

BAKKER, A ;

GEJJI, S ;

LINDGREN, J ;

HERMANSSON, K ;

PROBST, MM .

POLYMER, 1995, 36 (23) :4371-4378

[5]

BALDUCCI A, IN PRESS ELECTROCHIM

[6] Vibrational study of the structural phase transition in bis(pyrrolidinium)-chloride-hexachloroantimonate(V) by infrared spectroscopy [J].

Bednarska-Bolek, B ;

Jakubas, R ;

Bator, G ;

Baran, J .

JOURNAL OF MOLECULAR STRUCTURE, 2002, 614 (1-3) :151-157

[7] Group 15 quaternary alkyl bistrflimides: ionic liquids with potential application in electropositive metal deposition and as supporting electrolytes [J].

Bhatt, AI ;

May, I ;

Volkovich, VA ;

Hetherington, ME ;

Lewin, B ;

Thied, RC ;

Ertok, N .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2002, (24) :4532-4534

[8] Vibrational spectra and harmonic force fields of pyrrolidine derivatives: comparison between HF, MP2 and DFT force fields [J].

Billes, F ;

Geidel, E .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1997, 53 (14) :2537-2551

[9] Ionic liquid (molten salt) phase organometallic catalysis [J].

Dupont, J ;

de Souza, RF ;

Suarez, PAZ .

CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691

[10] Ionic liquids. Green solvents for the future [J].

Earle, MJ ;

Seddon, KR .

PURE AND APPLIED CHEMISTRY, 2000, 72 (07) :1391-1398