Investigation of oxidation and migration processes of inorganic compounds in ink-corroded manuscripts

被引：68

作者：

Kanngiesser, B

Hahn, O

Wilke, M

Nekat, B

Malzer, W

Erko, A

机构：

[1] Tech Univ Berlin, Inst Atom Phys & Fachdidakt, D-10623 Berlin, Germany

[2] Bundesanstalt Mat Forsch & Prufung, D-12203 Berlin, Germany

[3] Univ Potsdam, Inst Geowissensch, D-14415 Potsdam, Germany

[4] Berliner Elektronenspeicherring Gesell Synchrotro, D-12489 Berlin, Germany

来源：

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 2004年 / 59卷 / 10-11期

关键词：

X-ray fluorescence analysis; X-ray absorption near edge structure spectroscopy; archaeometry; iron gall ink corrosion;

D O I：

10.1016/j.sab.2004.07.013

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

We studied the oxidation and migration processes of inorganic compounds in iron gall inks with a combination of micro X-ray fluorescence analysis (micro-XRF) and micro X-ray absorption near edge structure spectroscopy (micro-XANES). With elemental mapping by micro-XRF, the correlation of the minor elements in the ink to the major element Fe was investigated. Along concentration profiles of Fe, micro-XANES measurements were carried out in order to determine the oxidation state and the local environment. With the help of model inks, we could show that Cu is a further important element in the paper degradation process due to iron gall ink corrosion. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1511 / 1516

页数：6

共 12 条

[1]

BANIK G, 1981, MIKROCHIM ACTA, V1, P49

[2]

Erko A, 2000, AIP CONF PROC, V521, P415, DOI 10.1063/1.1291824

[3]

EUSMAN E, 1999, ARTS SCI CONS COL ME

[4] Characterization of iron-gall inks in historical manuscripts and music compositions using x-ray fluorescence spectrometry [J].