Direct metalation of 1-alkynes using TiCl4/Et3N and the reactions of the organotitanium intermediates with electrophiles

被引:48
作者
Bharathi, P [1 ]
Periasamy, M [1 ]
机构
[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
关键词
D O I
10.1021/om000204o
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Alkynyltitanium reagents are prepared in situ in the reaction of 1-alkynes with TiCl4/Et3N and are used in the reaction with certain electrophiles.
引用
收藏
页码:5511 / 5513
页数:3
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