Adsorption kinetics of zeolite coatings directly crystallized on metal supports for heat pump applications (adsorption kinetics of zeolite coatings)

被引：72

作者：

Schnabel, Lena ^{[2
]}

Tatlier, Melkon ^{[1
]}

Schmidt, Ferdinand ^{[3
]}

Erdem-Senatalar, Aye ^{[1
]}

机构：

[1] Istanbul Tech Univ, Dept Chem Engn, TR-34469 Istanbul, Turkey

[2] Fraunhofer Inst Solar Energy Syst, D-79110 Freiburg, Germany

[3] Univ Karlsruhe, Res Grp Energy & Bldg Technol, D-76128 Karlsruhe, Germany

来源：

APPLIED THERMAL ENGINEERING | 2010年 / 30卷 / 11-12期

关键词：

Adsorption; Kinetics; Heat pump; Zeolite; Coating; MASS;

D O I：

10.1016/j.applthermaleng.2010.02.030

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A series of theoretical studies had previously indicated that the utilization of zeolite coatings directly crystallized on metal surfaces might improve the performance of adsorption heat pumps significantly. In this study, for the first time, kinetic measurements were performed to determine the rate of adsorption of zeolite coatings, which is the relevant parameter for increasing the power density of heat pump applications. The zeolite coatings investigated were prepared by using the substrate heating method. A scale-up of the substrate heating system was made in order to be able to grow zeolite coatings on 5 x 5 cm(2) stainless steel plates, instead of the 1 x 1 cm(2) plates, conventionally used in synthesis experiments. Two different reactors were constructed in which zeolite A and X coatings, with mass equivalent thicknesses of about 38 mu m and 230 mu m, respectively, could be obtained. The zeolite X coating, which had a quite open nature, exhibited quite favorable overall adsorption kinetics when compared to a reference sample, a paper-like polymer structure containing zeolite laminated on a metal layer. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1409 / 1416

页数：8

共 18 条

[1]

[Anonymous], P INT C SORPT HEAT P

[2] Hydrophilic and antimicrobial low-silica-zeolite LTA and high-silica-zeolite MFI hybrid coatings on aluminum alloys [J].

Beving, Derek E. ;

O'Neill, Cory R. ;

Yan, Yushan .

MICROPOROUS AND MESOPOROUS MATERIALS, 2008, 108 (1-3) :77-85

[3] Zeolite coated copper foams for heat pumping applications [J].

Bonaccorsi, L ;

Freni, A ;

Proverbio, E ;

Restuccia, G ;

Russo, F .

MICROPOROUS AND MESOPOROUS MATERIALS, 2006, 91 (1-3) :7-14

[4] Preparation of zeolite coatings by direct heating of the substrates [J].

Erdem-Senatalar, A ;

Tatlier, M ;

Ürgen, M .

MICROPOROUS AND MESOPOROUS MATERIALS, 1999, 32 (03) :331-343

[5] Enhancement of heat and mass transfer in silica-expanded graphite composite blocks for adsorption heat pumps: Part I. Characterization of the composite blocks [J].

Eun, TH ;

Song, HK ;

Han, JH ;

Lee, KH ;

Kim, JN .

INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID, 2000, 23 (01) :64-73

[6] An advanced solid sorption chiller using SWS-1Ll [J].

Freni, A. ;

Russo, F. ;

Vasta, S. ;

Tokarev, M. ;

Aristov, Yu. I. ;

Restuccia, G. .

APPLIED THERMAL ENGINEERING, 2007, 27 (13) :2200-2204

[7] HEAT-TRANSFER INTENSIFICATION IN FIXED-BED ADSORBERS [J].

GUILLEMINOT, JJ ;

CHOISIER, A ;

CHALFEN, JB ;

NICOLAS, S ;

REYMONEY, JL .

HEAT RECOVERY SYSTEMS & CHP, 1993, 13 (04) :297-300

[8]

GUILLEMINOT JJ, 1994, P INT ABS HEAT PUMP, V31, P401

[9]

JANSEN JC, 1994, STUD SURF SCI CATAL, V85, P215

[10]

Poyelle F., 1995, P 19 INT C REFR HA A, VIVa, P261

← 1 2 →