Structural properties of Li1+3V3O8 upon lithium insertion at ambient and high temperature

被引：70

作者：

Kawakita, J ^{[1
]}

Katayama, Y ^{[1
]}

Miura, T ^{[1
]}

Kishi, T ^{[1
]}

机构：

[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, Yokohama, Kanagawa 223, Japan

来源：

SOLID STATE IONICS | 1998年 / 107卷 / 1-2期

关键词：

lithium insertion; lithium vanadate; temperature; cell parameters;

D O I：

10.1016/S0167-2738(97)00523-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Lithium insertion behaviour of lithium vanadate, Li1.2V3O8, was investigated using both chemical and electrochemical methods at ambient and high temperature of 100 degrees C. Additional Li+ ions up to Li4V3O8 were accommodated under 2.5 V at 100 degrees C. Each of the cell parameters changed linearly in the single-phase region of x < 2.0 in Li1+xV3O8. A constant value was observed in the two-phase region of 2.0 < x < 3.0. Further lithium insertion beyond x > 3.2 lead to an increase in cell volume of the host structure.

引用

页码：145 / 152

页数：8

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