By-product formation causes leaching of Ti from the redox molecular sieve TS-1

被引：57

作者：

Davies, L

McMorn, P

Bethell, D

Page, PCB

King, F

Hancock, FE

Hutchings, GJ

机构：

[1] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales

[2] Univ Liverpool, Dept Chem, Liverpool L69 3BX, Merseyside, England

[3] Univ Loughborough, Dept Chem, Loughborough LE11 3TU, Leics, England

[4] Synetix, Billingham TS23 1LB, Cleveland, England

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 18期

关键词：

D O I：

10.1039/b002055i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triols, formed as by-products from the titanium silicalite (TS-1) catalysed epoxidation of allylic alcohols, can cause leaching of Ti from the microporous framework.

引用

页码：1807 / 1808

页数：2

共 12 条

[1] A NEW FAMILY OF MESOPOROUS MOLECULAR-SIEVES PREPARED WITH LIQUID-CRYSTAL TEMPLATES [J].

BECK, JS ;

VARTULI, JC ;

ROTH, WJ ;

LEONOWICZ, ME ;

KRESGE, CT ;

SCHMITT, KD ;

CHU, CTW ;

OLSON, DH ;

SHEPPARD, EW ;

MCCULLEN, SB ;

HIGGINS, JB ;

SCHLENKER, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10834-10843

[2] Synthesis and catalytic activity of aluminium-free zeolite Ti-beta oxidation catalysts [J].

Camblor, MA ;

Costantini, M ;

Corma, A ;

Gilbert, L ;

Esteve, P ;

Martinez, A ;

Valencia, S .

CHEMICAL COMMUNICATIONS, 1996, (11) :1339-1340

[3]

CARAVLHO WA, 1997, ZEOLITES, V18, P408

[4] EPOXIDATION OF LOWER OLEFINS WITH HYDROGEN-PEROXIDE AND TITANIUM SILICALITE [J].

CLERICI, MG ;

INGALLINA, P .

JOURNAL OF CATALYSIS, 1993, 140 (01) :71-83

[5] EPOXIDATION OF ALLYL ALCOHOL TO GLYCIDOL USING TITANIUM SILICALITE TS-1 - EFFECT OF THE METHOD OF PREPARATION [J].

HUTCHINGS, GJ ;

LEE, DF ;

MINIHAN, AR .

CATALYSIS LETTERS, 1995, 33 (3-4) :369-385

[6] Allylic oxidation of olefins to the corresponding alpha,beta-unsaturated ketones catalyzed by chromium aluminophosphate-5 [J].

Lempers, HEB ;

Sheldon, RA .

APPLIED CATALYSIS A-GENERAL, 1996, 143 (01) :137-143

[7] HYDROXYLATION OF PHENOL WITH HYDROGEN-PEROXIDE ON EUROTS-1 CATALYST [J].

MARTENS, JA ;

BUSKENS, P ;

JACOBS, PA ;

VANDERPOL, A ;

VANHOOFF, JHC ;

FERRINI, C ;

KOUWENHOVEN, HW ;

KOOYMAN, PJ ;

VANBEKKUM, H .

APPLIED CATALYSIS A-GENERAL, 1993, 99 (01) :71-84

[8] Heterogeneous catalysts for liquid-phase oxidations: Philosophers' stones or Trojan horses? [J].

Sheldon, RA ;

Wallau, M ;

Arends, IWCE ;

Schuchardt, U .

ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (08) :485-493

[9]

TARAMASSO M, 1983, Patent No. 4410510

[10]

TARAMASSO M, 1986, Patent No. 4666692

← 1 2 →