Synthesis and X-ray crystal structure of a p-confused carbaporphyrinoid

被引：15

作者：

Duan, Zheng

Clochard, Magali

Donnadieu, Bruno

Mathey, Francois ^{[1
]}

Tham, Fook S.

机构：

[1] Univ Calif Riverside, Dept Chem, UCR CNRS Joint Res Chem Lab, Ctr S & P Block Chem, Riverside, CA 92521 USA

[2] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

[3] Univ Calif Riverside, Dept Chem, Riverside, CA 92521 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 15期

关键词：

D O I：

10.1021/om700344q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of a phosphole-2,5-diol with a tripyrromethane in the presence of BF3 generates, after oxidation by DDQ, a P-confused carbaporphyrinoid whose X-ray crystal structure analysis has been performed. The steric bulk of the phosphorus subunit prevents the formation of the expected phosphaporphyrin.

引用

页码：3617 / 3620

页数：4

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