Photomediated asymmetric synthesis of (2)-cuparene

被引：22

作者：

Grainger, RS ^{[1
]}

Patel, A ^{[1
]}

机构：

[1] Kings Coll London, Dept Chem, London WC2R 2LS, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 09期

关键词：

D O I：

10.1039/b300815k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Generation of a benzylic quaternary stereocentre via the photomediated cyclisation of a chiral alpha-(aminobutyl)styrene followed by a microwave-assisted Cope elimination has led to a total synthesis of the sesquiterpene (-)-cuparene.

引用

页码：1072 / 1073

页数：2

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