Direct synthesis of methane from CO2-H2O co-electrolysis in tubular solid oxide electrolysis cells

被引:147
作者
Chen, Long [1 ,2 ]
Chen, Fanglin [3 ]
Xia, Changrong [1 ,2 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, CAS Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, Collaborat Innovat Ctr Suzhou Nano Sci & Technol, Hefei 230026, Anhui, Peoples R China
[3] Univ S Carolina, Dept Mech Engn, Columbia, SC 29208 USA
基金
中国国家自然科学基金; 美国国家科学基金会;
关键词
D O I
10.1039/c4ee02786h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Directly converting CO2 to hydrocarbons offers a potential route for carbon-neutral energy technologies. Here we report a novel design, integrating the high-temperature CO2-H2O co-electrolysis and low-temperature Fischer-Tropsch synthesis in a single tubular unit, for the direct synthesis of methane from CO2 with a substantial yield of 11.84%.
引用
收藏
页码:4018 / 4022
页数:5
相关论文
共 15 条
[1]   Steam electrolysis by solid oxide electrolysis cells (SOECs) with proton-conducting oxides [J].
Bi, Lei ;
Boulfrad, Samir ;
Traversa, Enrico .
CHEMICAL SOCIETY REVIEWS, 2014, 43 (24) :8255-8270
[2]   Anode substrate with continuous porosity gradient for tubular solid oxide fuel cells [J].
Chen, Long ;
Yao, Mutian ;
Xia, Changrong .
ELECTROCHEMISTRY COMMUNICATIONS, 2014, 38 :114-116
[3]   A review on exergy comparison of hydrogen production methods from renewable energy sources [J].
Christopher, Koroneos ;
Dimitrios, Rovas .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (05) :6640-6651
[4]   Syngas production via high-temperature steam/CO2 co-electrolysis: an economic assessment [J].
Fu, Qingxi ;
Mabilat, Corentin ;
Zahid, Mohsine ;
Brisse, Annabelle ;
Gautier, Ludmila .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (10) :1382-1397
[5]   Sustainable hydrocarbon fuels by recycling CO2 and H2O with renewable or nuclear energy [J].
Graves, Christopher ;
Ebbesen, Sune D. ;
Mogensen, Mogens ;
Lackner, Klaus S. .
RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2011, 15 (01) :1-23
[6]   Intermediate temperature solid oxide electrolysis cell using LaGaO3 based perovskite electrolyte [J].
Ishihara, Tatsumi ;
Jirathiwathanakul, Nitiphong ;
Zhong, Hao .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (05) :665-672
[7]   Performance and methane production characteristics of H2O-CO2 co-electrolysis in solid oxide electrolysis cells [J].
Li, Wenying ;
Wang, Hongjian ;
Shi, Yixiang ;
Cai, Ningsheng .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (25) :11104-11109
[8]  
McGee M., 399 00PPM ATMOSPHERI
[9]  
U. S. E. I. A. (EIA), SHORT TERM EN OUTL
[10]   Kinetics and selectivity of the Fischer-Tropsch synthesis: A literature review [J].
Van der Laan, GP ;
Beenackers, AACM .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 1999, 41 (3-4) :255-318