Fuzzy nanofibrous network of polyaniline electrode for supercapacitor application

被引:76
作者
Dhawale, D. S. [1 ]
Dubal, D. P. [1 ]
Jamadade, V. S. [1 ]
Salunkhe, R. R. [1 ]
Lokhande, C. D. [1 ]
机构
[1] Shivaji Univ, Dept Phys, Thin Film Phys Lab, Kolhapur 416004, Maharashtra, India
关键词
Fuzzy nanofibrous network; Polyaniline; Electrodeposition; Supercapacitor; COMPOSITE ELECTRODES; PERFORMANCE; BEHAVIOR;
D O I
10.1016/j.synthmet.2010.01.021
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fuzzy nanofibrous network of polyaniline electrode is successfully electrosynthesized for supercapacitor application. The nanofibre network of polyaniline electrode is characterized using Fourier transforms infrared spectroscopy (FTIR), scanning electron microscope (SEM) and optical absorption studies. Network of polyaniline is highly porous with interconnected fuzzy nanofibres having diameter typically between 120 and 125 nm. The supercapacitive performance of polyaniline electrode is tested using cyclic voltammetry (C-V) technique in H2SO4 electrolyte within potential range of -100 to 800 mV. The effect of scan rate on the capacitance of polyaniline electrode is studied. The highest specific capacitance of 839 Fg(-1) at the voltage scan rate of 10 mV s(-1) is achieved. Additionally stability and charging-discharging of polyaniline electrode are studied. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:519 / 522
页数:4
相关论文
共 23 条
[1]   Characterization and long-term performance of polyaniline-based electrochemical capacitors [J].
Bélanger, D ;
Ren, XM ;
Davey, J ;
Uribe, F ;
Gottesfeld, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (08) :2923-2929
[2]   Preparation of the novel nanocomposite Co(OH)2/ultra-stable Y zeolite and its application as a supercapacitor with high energy density [J].
Cao, L ;
Xu, F ;
Liang, YY ;
Li, HL .
ADVANCED MATERIALS, 2004, 16 (20) :1853-+
[3]   Polyaniline nanofibre supported platinum nanoelectrocatalysts for direct methanol fuel cells [J].
Chen, Zhongwei ;
Xu, Lianbin ;
Li, Wenzhen ;
Waje, Mahesh ;
Yan, Yushan .
NANOTECHNOLOGY, 2006, 17 (20) :5254-5259
[4]   Electrochemical characterization of polyaniline in nonaqueous electrolyte and its evaluation as electrode material for electrochemical supercapacitors [J].
Fusalba, F ;
Gouérec, P ;
Villers, D ;
Bélanger, D .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (01) :A1-A6
[5]   Electrochemical, electrochromic and photoelectrochemical behavior of a highly soluble polyaniline derivative: Poly(o-methoxyaniline) doped with functionalized organic acids [J].
Gazotti, WA ;
Faez, R ;
DePaoli, MA .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 415 (1-2) :107-113
[6]  
Gujar TP, 2007, INT J ELECTROCHEM SC, V2, P666
[7]   Large-area network of polyaniline nanowires prepared by potentiostatic deposition process [J].
Gupta, V ;
Miura, N .
ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (10) :995-999
[8]   Polyaniline/single-wall carbon nanotube (PANI/SWCNT) composites for high performance supercapacitors [J].
Gupta, Vinay ;
Miura, Norio .
ELECTROCHIMICA ACTA, 2006, 52 (04) :1721-1726
[9]   Influence of the microstructure on the supercapacitive behavior of polyaniline/single-wall carbon nanotube composites [J].
Gupta, Vinay ;
Miura, Norio .
JOURNAL OF POWER SOURCES, 2006, 157 (01) :616-620
[10]   A novel emulsion route to sub-micrometer polyaniline/nano-ZnO composite fibers [J].
He, YJ .
APPLIED SURFACE SCIENCE, 2005, 249 (1-4) :1-6