Experimental determination of solid-liquid interfacial energy for Zn solid solution in equilibrium with the Zn-Al eutectic liquid

被引:55
作者
Keslioglu, K [1 ]
Marasli, N [1 ]
机构
[1] Erciyes Univ, Fac Arts & Sci, Dept Phys, TR-38039 Kayseri, Turkey
来源
METALLURGICAL AND MATERIALS TRANSACTIONS A-PHYSICAL METALLURGY AND MATERIALS SCIENCE | 2004年 / 35A卷 / 12期
关键词
D O I
10.1007/s11661-004-0272-8
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The equilibrated grain boundary groove shapes for the Zn solid solution in equilibrium with the Zn-Al eutectic liquid were observed by rapid quenching. From the observed grain boundary groove shapes, the Gibbs-Thomson coefficient and the solid-liquid interfacial energy for the Zn solid solution in equilibrium with the Zn-Al eutectic liquid have been determined to be (5.80 +/- 0.18) X 10(-8) Km and (93.496 +/- 7.57) X 10(-3) Jm(-2) with the numerical method and from the Gibbs-Thomson equation, respectively. The grain boundary energy for the same material has been calculated to be (182.302 +/- 18.23) X 10(-3) Jm(-2) from the observed grain boundary groove shapes. The thermal conductivities of the solid and liquid phases for Zn-5 wt pct Al and Zn-0.5 wt pct Al alloys have also been measured.
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页码:3665 / 3672
页数:8
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