共 54 条
Improved electrochemical properties of prussian blue by multi-walled carbon nanotubes
被引:111
作者:
Li, Zhenfeng
[1
]
Chen, Jinhua
[1
]
Li, Wang
[1
]
Chen, Kun
[1
]
Nie, Lihua
[1
]
Yao, Shouzhuo
[1
]
机构:
[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Coll Chem & Chem Engn, Changsha 410082, Peoples R China
基金:
高等学校博士学科点专项科研基金;
中国国家自然科学基金;
关键词:
multi-walled carbon nanotube;
prussian blue;
electrochemistry;
hydrogen peroxide;
D O I:
10.1016/j.jelechem.2007.01.021
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
This paper reports on the greatly improved electrochemical properties of prussian blue (PB) by multi-walled carbon nanotubes (MWNTs). PB was efficiently deposited on the MWNTs modified pyrolytic graphite (PG) electrode. The microstructure and electrochemical behavior of the PG/MWNTs/PB electrodes were investigated by scanning electron microscopy and cyclic voltammetry, respectively. Compared with the PG/PB electrode, the PG/MWNTs/PB electrode shows much better electrochemical stability, much wider pH adaptive range and larger response current to the reduction of hydrogen peroxide (H2O2). Amperometric response of the PG/MWNTs/PB electrode to H2O2 at neutral solution pH was also investigated. (c) 2007 Elsevier B.V. All rights reserved.
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页码:59 / 66
页数:8
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