Improved electrochemical properties of prussian blue by multi-walled carbon nanotubes

被引:111
作者
Li, Zhenfeng [1 ]
Chen, Jinhua [1 ]
Li, Wang [1 ]
Chen, Kun [1 ]
Nie, Lihua [1 ]
Yao, Shouzhuo [1 ]
机构
[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Coll Chem & Chem Engn, Changsha 410082, Peoples R China
基金
高等学校博士学科点专项科研基金; 中国国家自然科学基金;
关键词
multi-walled carbon nanotube; prussian blue; electrochemistry; hydrogen peroxide;
D O I
10.1016/j.jelechem.2007.01.021
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
This paper reports on the greatly improved electrochemical properties of prussian blue (PB) by multi-walled carbon nanotubes (MWNTs). PB was efficiently deposited on the MWNTs modified pyrolytic graphite (PG) electrode. The microstructure and electrochemical behavior of the PG/MWNTs/PB electrodes were investigated by scanning electron microscopy and cyclic voltammetry, respectively. Compared with the PG/PB electrode, the PG/MWNTs/PB electrode shows much better electrochemical stability, much wider pH adaptive range and larger response current to the reduction of hydrogen peroxide (H2O2). Amperometric response of the PG/MWNTs/PB electrode to H2O2 at neutral solution pH was also investigated. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:59 / 66
页数:8
相关论文
共 54 条
[1]   Nanotubes from carbon [J].
Ajayan, PM .
CHEMICAL REVIEWS, 1999, 99 (07) :1787-1799
[2]   Metal-nanocluster-filled carbon nanotubes: Catalytic properties and possible applications in electrochemical energy storage and production [J].
Che, GL ;
Lakshmi, BB ;
Martin, CR ;
Fisher, ER .
LANGMUIR, 1999, 15 (03) :750-758
[3]   AMPEROMETRIC BIOSENSORS BASED ON THE IMMOBILIZATION OF OXIDASES IN A PRUSSIAN BLUE FILM BY ELECTROCHEMICAL CODEPOSITION [J].
CHI, QJ ;
DONG, SJ .
ANALYTICA CHIMICA ACTA, 1995, 310 (03) :429-436
[4]   ELECTRON-DIFFUSION IN WET AND DRY PRUSSIAN BLUE FILMS ON INTERDIGITATED ARRAY ELECTRODES [J].
FELDMAN, BJ ;
MURRAY, RW .
INORGANIC CHEMISTRY, 1987, 26 (11) :1702-1708
[5]   Electrocatalytic reactions of hydrogen peroxide at carbon paste electrodes modified by some metal hexacyanoferrates [J].
Garjonyte, R ;
Malinauskas, A .
SENSORS AND ACTUATORS B-CHEMICAL, 1998, 46 (03) :236-241
[6]   Operational stability of amperometric hydrogen peroxide sensors, based on ferrous and copper hexacyanoferrates [J].
Garjonyte, R ;
Malinauskas, A .
SENSORS AND ACTUATORS B-CHEMICAL, 1999, 56 (1-2) :93-97
[7]   Nanostructuring electrodes with carbon nanotubes: A review on electrochemistry and applications for sensing [J].
Gooding, JJ .
ELECTROCHIMICA ACTA, 2005, 50 (15) :3049-3060
[8]   CARBON-PASTE ELECTRODES MODIFIED WITH ENZYMES, TISSUES, AND CELLS [J].
GORTON, L .
ELECTROANALYSIS, 1995, 7 (01) :23-45
[9]   Fabrication of polyaniline/carbon nanotube composite modified electrode and its electrocatalytic property to the reduction of nitrite [J].
Guo, ML ;
Chen, JH ;
Li, J ;
Tao, B ;
Yao, SZ .
ANALYTICA CHIMICA ACTA, 2005, 532 (01) :71-77
[10]   Studies on the anode catalysts of carbon nanotube for DMFC [J].
Han, KI ;
Lee, JS ;
Park, SO ;
Lee, SW ;
Park, YW ;
Kim, H .
ELECTROCHIMICA ACTA, 2004, 50 (2-3) :791-794