Change in entropy at a first-order magnetoelastic phase transition:: Case study of Gd5(SixGe1-x)4 giant magnetocaloric alloys

被引:19
作者
Casanova, F
Batlle, X
Labarta, A
Marcos, J
Mañosa, L
Planes, A
机构
[1] Univ Barcelona, Dept Fis Fonamental, E-08028 Barcelona, Catalonia, Spain
[2] Univ Barcelona, Dept Estructura & Constituents Mat, E-08028 Barcelona, Catalonia, Spain
关键词
D O I
10.1063/1.1556274
中图分类号
O59 [应用物理学];
学科分类号
摘要
The change in entropy, DeltaS, at the first-order magnetoelastic phase transition in Gd-5(SixGe1-x)(4) alloys for xless than or equal to0.5 has been measured with a high-sensitivity differential scanning calorimeter with built-in magnetic field, H. Scaling of DeltaS is achieved by changing the transition temperature, T-t, with x and H from 70 to 310 K. T-t is thus the relevant parameter in determining the giant magnetocaloric effect in these alloys. The calorimetric determination of the change in entropy is also in agreement with the indirect calculation obtained from the magnetization curves measured up to 23 T using both the Clausius-Clapeyron equation and the Maxwell relation. A simple phenomenological model based on the magnetization curves accounts for these results. (C) 2003 American Institute of Physics.
引用
收藏
页码:8313 / 8315
页数:3
相关论文
共 13 条
[1]   Entropy change and magnetocaloric effect in Gd5(SixGe1-x)4 -: art. no. 100401 [J].
Casanova, F ;
Batlle, X ;
Labarta, A ;
Marcos, J ;
Mañosa, L ;
Planes, A .
PHYSICAL REVIEW B, 2002, 66 (10) :1-4
[2]   Scaling of the entropy change at the magnetoelastic transition in Gd5(SixGe1-x)4 -: art. no. 212402 [J].
Casanova, F ;
Batlle, X ;
Labarta, A ;
Marcos, J ;
Mañosa, L ;
Planes, A .
PHYSICAL REVIEW B, 2002, 66 (21) :1-4
[3]   Making and breaking covalent bonds across the magnetic transition in the giant magnetocaloric material Gd5(Si2Ge2) [J].
Choe, W ;
Pecharsky, VK ;
Pecharsky, AO ;
Gschneidner, KA ;
Young, VG ;
Miller, GJ .
PHYSICAL REVIEW LETTERS, 2000, 84 (20) :4617-4620
[4]   Comment on "Direct measurement of the 'giant' adiabatic temperature change in Gd5Si2Ge2" -: Reply [J].
Földeàki, M ;
Chahine, R ;
Bose, TK ;
Barclay, JA .
PHYSICAL REVIEW LETTERS, 2000, 85 (19) :4192-4192
[5]   Direct measurement of the "giant" adiabatic temperature change in Gd5Si2Ge2 [J].
Giguère, A ;
Foldeaki, M ;
Gopal, BR ;
Chahine, R ;
Bose, TK ;
Frydman, A ;
Barclay, JA .
PHYSICAL REVIEW LETTERS, 1999, 83 (11) :2262-2265
[6]   Comment on "Direct measurement of the 'giant' adiabatic temperature change in Gd5Si2Ge2" [J].
Gschneidner, KA ;
Pecharsky, VK ;
Brück, E ;
Duijn, HGM ;
Levin, EM .
PHYSICAL REVIEW LETTERS, 2000, 85 (19) :4190-4190
[7]   *INFLUENCE DU CHAMP MAGNETIQUE SUR UNE TRANSFORMATION POLYMORPHIQUE DUN FERROMAGNETIQUE [J].
MEYER, AJP ;
TAGLANG, P .
JOURNAL DE PHYSIQUE ET LE RADIUM, 1953, 14 (02) :82-84
[8]   Nature of the first-order antiferromagnetic-ferromagnetic transition in the Ge-rich magnetocaloric compounds Gd5(SixGe1-x)4 [J].
Morellon, L ;
Blasco, J ;
Algarabel, PA ;
Ibarra, MR .
PHYSICAL REVIEW B, 2000, 62 (02) :1022-1026
[9]   Magnetic-field-induced structural phase transition in Gd5(Si1.8Ge2.2) [J].
Morellon, L ;
Algarabel, PA ;
Ibarra, MR ;
Blasco, J ;
García-Landa, B ;
Arnold, Z ;
Albertini, F .
PHYSICAL REVIEW B, 1998, 58 (22) :R14721-R14724
[10]   Giant magnetocaloric effect in Gd-5(Si2Ge2) [J].
Pecharsky, VK ;
Gschneidner, KA .
PHYSICAL REVIEW LETTERS, 1997, 78 (23) :4494-4497