Ultrasonic effects on electroorganic processes.: Part 26.: Current efficiency and product selectivity in the anodic cyanation of N-methylpyrrole

被引：4

作者：

Atobe, M

Aoyagi, T

Fuchigami, T

Nonaka, T

机构：

[1] Tokyo Inst Technol, Dept Elect Chem, Midori Ku, Yokohama, Kanagawa 2268502, Japan

[2] Tsuruoka Natl Coll Technol, Tsuruoka 9978511, Japan

来源：

ELECTROCHEMISTRY | 2004年 / 72卷 / 12期

关键词：

sonoelectrochemistry; ultrasonication; product selectivity; anodic cyanation; N-methylpyrrole;

D O I：

10.5796/electrochemistry.72.821

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Ultrasonic effect on the anodic cyanation of N-methylpyrrole was examined. Current efficiency and product selectivity for the monocyanated product formed by two-electrons oxidation along with dicyanated product formed by four-electrons oxidation, were significantly increased under ultrasonication. Moreover, it was also found that considerably high efficiency and selectivity could be obtained under ultrasonication even if the concentration of cyanide as a nucleophile was decreased. Ibis is desirable from an environmental viewpoint.

引用

页码：821 / 823

页数：3

共 15 条

[1] Ultrasonic effects on electroorganic processes. Part 22. Cathodic crossed hydrocoupling of acetone with acrylonitrile [J].