Self-construction of hollow SnO2 octahedra based on two-dimensional aggregation of nanocrystallites

被引：417

作者：

Yang, HG ^{[1
]}

Zeng, HC ^{[1
]}

机构：

[1] Natl Univ Singapore, Fac Engn, Dept Chem & Biomol Engn, Singapore 119260, Singapore

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 44期

关键词：

hydrothermal synthesis; nanostructures; oriented attachment; self-assembly; tin oxide;

D O I：

10.1002/anie.200461129

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

OD→2D→3D oriented attachment has been exploited to prepare octahedra of rutile-like SnO2 with a central cavity by a template-free hydrothermal route. The synthesis is based on the two-dimensional attachment of nanocrystallites and stabilization of a family of {111}-like crystal planes in 2-propanol/water in the presence of ethylenediamine. In TEM images of the octahedron (see picture), the central cavity is evidenced by lighter regions.

引用

页码：5930 / 5933

页数：4

共 24 条

[1]

Caruso F, 2001, ADV MATER, V13, P11, DOI 10.1002/1521-4095(200101)13:1<11::AID-ADMA11>3.0.CO

[2]

2-N

[3] Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating [J].

Caruso, F ;

Caruso, RA ;

Möhwald, H .

SCIENCE, 1998, 282 (5391) :1111-1114

[4] Tin oxide nanowires, nanoribbons, and nanotubes [J].

Dai, ZR ;

Gole, JL ;

Stout, JD ;

Wang, ZL .

JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (06) :1274-1279

[5] Growth and structure evolution of novel tin oxide diskettes [J].

Dai, ZR ;

Pan, ZW ;

Wang, ZL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (29) :8673-8680

[6] Colloidosomes: Selectively permeable capsules composed of colloidal particles [J].

Dinsmore, AD ;

Hsu, MF ;

Nikolaides, MG ;

Marquez, M ;

Bausch, AR ;

Weitz, DA .

SCIENCE, 2002, 298 (5595) :1006-1009

[7] Single-crystal gallium nitride nanotubes [J].

Goldberger, J ;

He, RR ;

Zhang, YF ;

Lee, SW ;

Yan, HQ ;

Choi, HJ ;

Yang, PD .

NATURE, 2003, 422 (6932) :599-602

[8]

Goltner C. G., 1999, ANGEW CHEM, V111, P3347

[9]

Göltner CG, 1999, ANGEW CHEM INT EDIT, V38, P3155

[10] Fabrication of mesoporous core-shell structured titania microspheres with hollow interiors [J].

Guo, CW ;

Cao, Y ;

Xie, SH ;

Dai, WL ;

Fan, KN .

CHEMICAL COMMUNICATIONS, 2003, (06) :700-701

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