Spheres in laser material studies or useful simplifications brought by 'ascending' symmetries

被引:3
作者
Auzel, F [1 ]
机构
[1] DIPC, Basque Country 20018, Spain
[2] Univ Basque Country, Escuela Super Ingenieros, Dept Fis Aplicada 1, E-48080 Bilbao, Spain
[3] FAConseils, F-78320 Le Mesnil St Denis, France
关键词
D O I
10.1080/00268970410001728825
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is shown that looking for quasi-spheres allows one to describe the complex spectra of an Er3+-doped silicate glass near 1500 nm in a simple way. It is shown that 'ascending' the symmetry from the generally accepted point symmetry C-2v to the pure icosahedral symmetry, brings practical simplification. Looking for a spherical approximation in the crystal field parameter space, brings further simplification through use of the N-v scalar crystal field parameter describing the maximum crystal field splitting of a given J-state. The B-0(6), B-3(6) and B-6(6) icosahedral crystal field values are deduced from it. Such effective ascending symmetry may be of practical importance knowing that the considered I-4(13/2) <----> I-4(15/2) transition of Er3+ in silica glasses rules the universally adopted optical amplification in glass fibre telecommunication networks.
引用
收藏
页码:1113 / 1118
页数:6
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