Neutron diffraction studies of Pb(ZrxTi1-x)O3 ceramics

被引:83
作者
Frantti, J
Lappalainen, J
Eriksson, S
Lantto, V
Nishio, S
Kakihana, M
Ivanov, S
Rundlöf, H
机构
[1] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Oulu Univ, Microelect & Mat Phys Labs, FIN-90014 Oulu, Finland
[3] Uppsala Univ, Studsvik Neutron Res Lab, S-61182 Nykoping, Sweden
[4] Karpov Inst Phys Chem, Dept Inorgan Mat, Xray Lab, Moscow 103064, Russia
来源
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS | 2000年 / 39卷 / 9B期
关键词
lead zirconate titanate; tetragonal; monoclinic; phase transition; neutron diffraction;
D O I
10.1143/JJAP.39.5697
中图分类号
O59 [应用物理学];
学科分类号
摘要
Neutron diffraction studies of lead zirconate titanate Pb(ZrxT1-x)O-3 (PZT) powders, 0.20 less than or equal to x less than or equal to 0.54, were carried out at 10 K and 297 K, The phase transition predicted by our earlier Raman observations (J. Frantti, J. Lappalainen, V. Lantto, S. Nishio and M. Kakihana: Jpn. J. Appl: Phys. 38 (1999) 5679) was confirmed. The importance of the A- and B-cation displacements in structural changes as a function of Zr content is discussed.
引用
收藏
页码:5697 / 5703
页数:7
相关论文
共 10 条
[1]  
CARVAJAL JR, 1998, PROGRAM FULLPROF RIE
[2]   A neutron diffraction investigation into the rhombohedral phases of the perovskite series PbZr1-xTixO3 [J].
Corker, DL ;
Glazer, AM ;
Whatmore, RW ;
Stallard, A ;
Fauth, F .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (28) :6251-6269
[3]   Effect of A- and B-cation substitutions on the phase stability of PbTiO3 ceramics [J].
Frantti, J ;
Lantto, V ;
Nishio, S ;
Kakihana, M .
PHYSICAL REVIEW B, 1999, 59 (01) :12-15
[4]   Low-temperature Raman studies of Pb(ZrxTi1-x)O3 and Pb1-3y/2NdyTiO3 ceramics [J].
Frantti, J ;
Lappalainen, J ;
Lantto, V ;
Nishio, S ;
Kakihana, M .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1999, 38 (9B) :5679-5682
[5]  
LARSON AC, MSH805 LANSCE LOS AL
[6]   Temperature-dependent neutron powder diffraction evidence for splitting of the cationic sites in ferroelectric PbHf0.4Ti0.6O3 [J].
Muller, C ;
Baudour, JL ;
Madigou, V ;
Bouree, F ;
Kiat, JM ;
Favotto, C ;
Roubin, M .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1999, 55 :8-16
[7]   Pulsed neutron diffraction study of Zr-rich PZT [J].
Noheda, B ;
Gonzalo, JA ;
Hagen, M .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1999, 11 (20) :3959-3965
[8]   Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite:: The structure of PbZr0.52Ti0.48O3 [J].
Noheda, B ;
Gonzalo, JA ;
Cross, LE ;
Guo, R ;
Park, SE ;
Cox, DE ;
Shirane, G .
PHYSICAL REVIEW B, 2000, 61 (13) :8687-8695
[9]  
Suortti P., 1972, Journal of Applied Crystallography, V5, P325, DOI 10.1107/S0021889872009707
[10]   Neutron scattering studies of compositional heterogeneity in sol-gel processed lead zirconate titanates [J].
Wilkinson, AP ;
Xu, J ;
Pattanaik, S ;
Billinge, SJL .
CHEMISTRY OF MATERIALS, 1998, 10 (11) :3611-3619