Copper complex cation templated gadolinium(III) - Isophthalate frameworks

被引：200

作者：

Zhou, YF ^{[1
]}

Jiang, FL ^{[1
]}

Yuan, DQ ^{[1
]}

Wu, BL ^{[1
]}

Wang, RH ^{[1
]}

Lin, ZZ ^{[1
]}

Hong, MC ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 42期

关键词：

copper; gadolinium; inclusion compounds; magnetic properties;

D O I：

10.1002/anie.200460919

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Ions in cages: Hydrothermal reactions give two novel 3D heterometallic frameworks, [{[Gd4(ip)7(H2O) 2][Cu(bpy)2]2}n] (1, bpy = 2,2′-bipyridine, H2ip = isophthalic acid; see structure, space filling models: [Cu(bpy)2], polyhedra: Gd) and [(Gd 3Cu(Ip)5(HiP) (bpy)}n]·n H2O (2). The structure of 1 consists of charged cages containing two encapsulated CuI complex cations, whereas that of 2 contains charged cavities in which CuII complex cations are bound.

引用

页码：5665 / 5668

页数：4

共 59 条

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[2]

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