Synthesis and metal-binding properties of [60]fullerene-linked calix[4]arenes: an approach to 'exohedral metallofullerenes'

被引：30

作者：

Kawaguchi, M ^{[1
]}

Ikeda, A ^{[1
]}

Shinkai, SJ ^{[1
]}

机构：

[1] Kyushu Univ, Fac Engn, Dept Chem Sci & Technol, Fukuoka 812, Japan

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1998年 / 02期

关键词：

D O I：

10.1039/a707258i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

'Fullerenocalixarenes' in which [60]fullerene is covalently linked through two ionophoric chains to a cone-calix[4]arene 1 or to a 1,3-alternate calix[4]arene 2 have been synthesized for the first time: although the absorption spectrum of 2 is scarcely changed upon addition of metal cations, that of 1 is affected by added Li+, Na+ and Ag+, indicating the formation of exohedral [60]fullerene-metal complexes.

引用

页码：179 / 184

页数：6

共 40 条

[1] [Anonymous], 1910, J. Physiol., DOI [DOI 10.1017/CBO9781107415324.004, DOI 10.1113/JPHYSIOL.1910.SP001386]
[2] Molecular design of calixarene-based host molecules for inclusion of C-60 in solution
Araki, K
Akao, K
Ikeda, A
Suzuki, T
Shinkai, S
[J]. TETRAHEDRON LETTERS, 1996, 37 (01) : 73 - 76
[3] PURIFICATION OF C-60 AND C-70 BY SELECTIVE COMPLEXATION WITH CALIXARENES
ATWOOD, JL
KOUTSANTONIS, GA
RASTON, CL
[J]. NATURE, 1994, 368 (6468) : 229 - 231
[4] Benesi H.A., 1949, J AM CHEM SOC, V71, P2073
[5] BETHUNE DS, 1993, NATURE, V123, P366
[6] CALIXARENES, MACROCYCLES WITH (ALMOST) UNLIMITED POSSIBILITIES
BOHMER, V
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (07): : 713 - 745
[7] CASNATI A, 1992, ISRAEL J CHEM, V32, P79
[8] C-60-AZACROWN ETHERS - THE FIRST MONOAMINATED FULLERENE DERIVATIVES
DAVEY, SN
LEIGH, DA
MOODY, AE
TETLER, LW
WADE, FA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (04) : 397 - 398
[9] SYNTHESIS OF A FULLERENE DERIVATIVE OF BENZO[18]CROWN-6 BY DIELS-ALDER REACTION - COMPLEXATION ABILITY, AMPHIPHILIC PROPERTIES, AND X-RAY CRYSTAL-STRUCTURE OF A DIMETHOXY-1,9-(METHANO[1,2]BENZENOMETHANO)FULLERENE[60]BENZENE CLATHRATE
DIEDERICH, F
JONAS, U
GRAMLICH, V
HERRMANN, A
RINGSDORF, H
THILGEN, C
[J]. HELVETICA CHIMICA ACTA, 1993, 76 (07) : 2445 - 2453
[10] Cation-pi interactions in chemistry and biology: A new view of benzene, Phe, Tyr, and Trp
Dougherty, DA
[J]. SCIENCE, 1996, 271 (5246) : 163 - 168

← 1 2 3 4 →