Functionalisation of monolayer-modified electrodes by covalent coupling of o-phenylenediamine monomer molecules

被引：15

作者：

Krysinski, P ^{[1
]}

Jackowska, K ^{[1
]}

Mazur, M ^{[1
]}

Tagowska, M ^{[1
]}

机构：

[1] Univ Warsaw, Dept Chem, Lab Electrochem, PL-02093 Warsaw, Poland

来源：

ELECTROCHIMICA ACTA | 2000年 / 46卷 / 2-3期

关键词：

electrochemical properties; alkanethiol monolayers; electrodes;

D O I：

10.1016/S0013-4686(00)00577-6

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemical properties of self-assembled alkanethiol monolayers on polycrystalline gold electrodes were studied by means of cyclic voltammetry (CV). These films were functionalized by covalent coupling of the o-phenylenediamine (o-PDA) monomer molecules to the alkanethiol monomolecular him, such as to form the centers for further electropolymerization reaction on the surface of the film. The rationale behind this a pp roach was to form the molecular 'wires' of conducting polymer with their structure imposed by the molecular organization of a monolayer and by the covalent linkage of the monomer molecules. (C) 2000 Elsevier Science Ltd. All rights reserved.

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页码：231 / 237

页数：7

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