Oxaaza cyclophanes in the recognition of nucleotides.: The role of oxygen and electron-rich aromatic rings

被引:17
作者
Burguete, M. I. [1 ]
Garcia-Espana, E.
Lopez-Diago, L.
Luis, S. V.
Miravet, J.
Sroczynski, D.
机构
[1] Univ Jaume 1, CSIC, Dept Inorgan & Organ Chem, E-12071 Castellon de La Plana, Spain
[2] Univ Valencia, Inst Ciencia Mol, Dept Inorgan Chem, Valencia 46071, Spain
关键词
D O I
10.1039/b704305h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Dioxapolyaza cyclophanes derived from resorcinol and different polyamine chains have been studied in aqueous solution as abiotic receptors for nucleotides. The presence of the additional ethyleneoxy subunits is reflected in a higher basicity and in a significant increase in the log K values for the interaction with nucleotides relative to that of related polyazacyclophanes.
引用
收藏
页码:1935 / 1944
页数:10
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