Formation and structural features of novel cage compounds with a pentacyclo[6.4.0.03,7.04,11.05,10]dodecane skeleton via photolysis of [33](1,3,5)cyclophane

被引：20

作者：

Matohara, K

Lim, C

Yasutake, M

Nogita, R

Koga, T

Sakamoto, Y

Shinmyozu, T ^{[1
]}

机构：

[1] Kyushu Univ, IFOC, Inst Fundamental Res Organ Chem, Fukuoka 8128581, Japan

[2] Kyushu Univ, Grad Sch Sci, Dept Chem, Fukuoka 8128581, Japan

[3] Inst Mol Sci, Okazaki, Aichi 4448585, Japan

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 35期

关键词：

hexaprismane; photolysis; cyclophanes; polycyclic cage compounds;

D O I：

10.1016/S0040-4039(00)01152-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The photolysis of [3(3)](1,3,5)cyclophane 8 in MeOH:2N HCl (17:1 v/v) afforded new polycyclic caged dimethoxy and methoxy-hydroxy compounds 12 and 13 with a novel pentacyclo[6.4.0.0(3,7).0(4,11).0(5,10)]- dodecane skeleton 7, in addition to methyl ether 9c with the previously reported skeleton 6. The unique structural features of 12 and 13 were elucidated by X-ray structural analysis. (C) 2000 Elsevier Science Ltd. All rights reserved.

引用

页码：6803 / 6807

页数：5

共 23 条

[1] Synthesis of a propella[4(4)]prismane with averaged S-4 symmetry [J].