Palladium-mediated approach to dibenzo[b,e][1,4]diazepines and benzopyrido-analogues.: An efficient synthesis of tarpane

被引：73

作者：

Beccalli, EM

Broggini, G

Paladino, G

Zoni, C

机构：

[1] Univ Milan, Fac Farm, Ist Chim Organ A Marchesini, I-20133 Milan, Italy

[2] Univ Insubria, Dipartimento Sci Chim & Ambientali, I-22100 Como, Italy

来源：

TETRAHEDRON | 2005年 / 61卷 / 01期

关键词：

Pd-catalyst; dibenzodiazepines; intramolecular cyclization; tarpane; Buchwald-Hartwig amination;

D O I：

10.1016/j.tet.2004.10.061

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An original synthetic route toward dibenzo[b,e] [ 1,4]diazepin-11-ones and analogues pyridobenzodiazepinones has been developed. The method relies upon an intramolecular amination process between an (hetero)aryl halide and the appropriate aniline moiety. (C) 2004 Elsevier Ltd. All rights reserved.

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页码：61 / 68

页数：8

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