Preparation, characterization and application of KNH2/Al2O3 and KF/Al2O3 as strong solid bases

被引：20

作者：

Baba, T ^{[1
]}

机构：

[1] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Appl Chem, Meguro Ku, Tokyo 1528552, Japan

来源：

CATALYSIS SURVEYS FROM JAPAN | 2000年 / 4卷 / 01期

关键词：

solid base catalysts; base strength; KNH2 on Al2O3; KF on Al2O3; isomerization of alkenes; dimerization of alkynes; Tishchenko reaction; reaction of silanes;

D O I：

10.1023/A:1019092222785

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This review describes the preparation, characterization and application of KNH2 loaded on alumina and KF loaded on alumina. These strong solid bases catalyze a variety of organic reactions in a very selective manner. The reactions include isomerizations of alkenes and alkynes, dimerization of alkynes, Tishchenko reaction, and the reaction of silanes to form of Si-C, Si-N and Si-O bonds.

引用

页码：17 / 29

页数：13

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