The catalytic intermolecular orthoarylation of phenols

被引：302

作者：

Bedford, RB ^{[1
]}

Coles, SJ

Hursthouse, MB

Limmert, ME

机构：

[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England

[2] Univ Southampton, EPSRC Natl Crystallog Serv, Southampton, Hants, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 01期

关键词：

arylation; homogeneous catalysis; P ligands; phenols; rhodium;

D O I：

10.1002/anie.200390037

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of Wilkinson's catalyst with diisopropylphosphinite ligands acting as cocatalysts allows the catalytic orthoarylation of phenols [Eq. (1)], a process that relies on a C-H activation of a phenol that has been incorporated into the cocatalyst by transesterification.

引用

页码：112 / 114

页数：3

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