Mineralization of an azo dye Acid Red 14 by electro- Fenton's reagent using an activated carbon fiber cathode

被引:290
作者
Wang, AM [1 ]
Qu, JH [1 ]
Ru, J [1 ]
Liu, HJ [1 ]
Ge, JT [1 ]
机构
[1] Chinese Acad Sci, State Key Lab Environm Aquat Chem, Res Ctr Ecoenvironm Sci, Beijing 100085, Peoples R China
基金
中国国家自然科学基金;
关键词
activated carbon fiber; electro-Fenton reaction; Acid Red 14; H2O electrogeneration;
D O I
10.1016/j.dyepig.2004.07.019
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this paper, the comparison of activated carbon fiber (ACF) felt and graphite cathode suggested H2O2 might effectively be electrogenerated from O-2 reduction on the large surface area ACF felt cathode. this was more adaptive for electro-Fenton process. The removal of color and total organic carbon (TOC) from simulated dye wastewater containing Acid Red 14 (ARIA) was experimentally investigated using electro-Fenton reaction with ACF cathode. After 360 min of electrolysis and under the operation conditions of 0.36 A current, 1 mM Fe2+ at pH 3, 70% TOC was removed as well as complete decolorization occurred. The effect of Fe2+ ion concentration and applied current were also studied in detail in the experimental runs. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:227 / 233
页数:7
相关论文
共 31 条
[1]   The removal of low level organics via hydrogen peroxide formed in a reticulated vitreous carbon cathode cell, Part 1. The electrosynthesis of hydrogen peroxide in aqueous acidic solutions [J].
Alvarez-Gallegos, A ;
Pletcher, D .
ELECTROCHIMICA ACTA, 1998, 44 (05) :853-861
[2]   The removal of low level organics via hydrogen peroxide formed in a reticulated vitreous carbon cathode cell. Part 2: The removal of phenols and related compounds from aqueous effluents [J].
Alverez-Gallegos, A ;
Pletcher, D .
ELECTROCHIMICA ACTA, 1999, 44 (14) :2483-2492
[3]   The role of hydroxyl radicals for the decomposition of p-hydroxy phenylacetic acid in aqueous solutions [J].
Benitez, FJ ;
Acero, JL ;
Real, FJ ;
Rubio, FJ ;
Leal, AI .
WATER RESEARCH, 2001, 35 (05) :1338-1343
[4]   Degradation of herbicide 4-chlorophenoxyacetic acid by advanced electrochemical oxidation methods [J].
Boye, B ;
Dieng, MM ;
Brillas, E .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2002, 36 (13) :3030-3035
[5]   ELECTROCHEMICAL DESTRUCTION OF ANILINE AND 4-CHLOROANILINE FOR WASTE-WATER TREATMENT USING A CARBON-PTFE O-2-FED CATHODE [J].
BRILLAS, E ;
BASTIDA, RM ;
LLOSA, E ;
CASADO, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1995, 142 (06) :1733-1741
[6]   Aniline mineralization by AOP's: anodic oxidation, photocatalysis, electro-Fenton and photoelectro-Fenton processes [J].
Brillas, E ;
Mur, E ;
Sauleda, R ;
Sanchez, L ;
Peral, J ;
Domenech, X ;
Casado, J .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 16 (01) :31-42
[7]   Iron(II) catalysis of the mineralization of aniline using a carbon-PTFE O-2-fed cathode [J].
Brillas, E ;
Mur, E ;
Casado, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (03) :L49-L53
[8]   Mineralization of 2,4-D by advanced electrochemical oxidation processes [J].
Brillas, E ;
Calpe, JC ;
Casado, J .
WATER RESEARCH, 2000, 34 (08) :2253-2262
[9]   Electrochemical degradation of chlorophenoxy and chlorobenzoic herbicides in acidic aqueous medium by the peroxi-coagulation method [J].
Brillas, E ;
Boye, B ;
Baños, MA ;
Calpe, JC ;
Garrido, JA .
CHEMOSPHERE, 2003, 51 (04) :227-235
[10]   Aniline degradation by Electro-Fenton® and peroxi-coagulation processes using a flow reactor for wastewater treatment [J].
Brillas, E ;
Casado, J .
CHEMOSPHERE, 2002, 47 (03) :241-248