New synthesis of quinoxaline derivatives based on palladium catalyzed oligomerization of 1-diisocyano-arenes

被引：15

作者：

Ito, Y

Kojima, Y

Suginome, M

Murakami, M

机构：

来源：

HETEROCYCLES | 1996年 / 42卷 / 02期

关键词：

D O I：

10.3987/COM-95-S51

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Various 2,3-disubstituted quinoxaline derivatives were synthesized from monomeric and oligomeric (3-substituted quinoxaline-2-yl)palladium(II)s, which were prepared by the reaction of o-diisocyanoarenes with trans-bromo(methyl)bis(phosphine)palladium(II).

引用

收藏

页码：597 / 615

页数：19

相关论文

共 9 条

[1]

CANDLIN JP, 1968, REACTIONS TRANSITION, P119

[2] POLY(IMINOMETHYLENES) - RIGID ROD HELICAL POLYMERS [J].

DRENTH, W ;

NOLTE, RJM .

ACCOUNTS OF CHEMICAL RESEARCH, 1979, 12 (01) :30-35

[3] NEW LIVING POLYMERIZATION OF 1,2-DIISOCYANOARENES VIA (QUINOXALINYL)PALLADIUM COMPLEXES - SYNTHESIS OF POLY(2,3-QUINOXALINE) [J].

ITO, Y ;

IHARA, E ;

MURAKAMI, M ;

SHIRO, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (17) :6446-6447

[4] ENANTIOSELECTIVE POLYMERIZATION OF 1,2-DIISOCYANOARENES - SYNTHESIS OF OPTICALLY-ACTIVE, HELICAL POLY(QUINOXALINE-2,3-DIYL)S [J].

ITO, Y ;

IHARA, E ;

MURAKAMI, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (11) :1509-1510

[5] SCREW-SENSE SELECTIVE SELF-PROPELLING POLYMERIZATIONS PRODUCING CHIRAL POLY(QUINOXALINE-2,3-DIYL)S [J].

ITO, Y ;

KOJIMA, Y ;

MURAKAMI, M .

TETRAHEDRON LETTERS, 1993, 34 (51) :8279-8282

[6]

KATRITZKY AR, COMPREHENSIVE HETERO, V3, P195

[7]

KOVALENKO M, 1994, CANCER RES, V54, P6106

[8] SIGMA-ALKYL OR SIGMA-ACYL ISOCYANIDE COMPLEXES OF NICKEL(II) AND PALLADIUM(II) . PREPARATION AND SUCCESSIVE INSERTION REACTIONS [J].

OTSUKA, S ;

NAKAMURA, A ;

YOSHIDA, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (25) :7196-&

[9] STUDIES ON INTERACTIONS OF ISOCYANIDES WITH TRANSITION-METAL COMPLEXES .9. SINGLE AND MULTIPLE INSERTION OF ISOCYANIDE INTO PALLADIUM-TO-CARBON SIGMA BONDS [J].

YAMAMOTO, Y ;

YAMAZAKI, H .

INORGANIC CHEMISTRY, 1974, 13 (02) :438-443