Chromium(VI) binding to functionalized silica/water interfaces studied by nonlinear optical spectroscopy

被引：37

作者：

Al-Abadleh, HA ^{[1
]}

Voges, AB ^{[1
]}

Bertin, PA ^{[1
]}

Nguyen, SBT ^{[1
]}

Geiger, FM ^{[1
]}

机构：

[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 36期

关键词：

D O I：

10.1021/ja048063v

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Organic adlayers can significantly alter the interactions of environmentally relevant surfaces with their surroundings. We present the first second harmonic and broadband sum frequency generation (SHG and BBSFG) study that illustrates how organic surface functional groups can control the mobility of the priority pollutant chromium(VI) in soil: Cr(VI) binds to ester- and acid-functionalized surfaces but not to alkane-functionalized surfaces. The implications with respect to toxic metal transport across organic adlayers at liquid-solid interfaces are that aqueous Cr(VI) can be retained by polar groups common in biopolymers but not by hydrophobic groups common in surfactants. Copyright © 2003 American Chemical Society.

引用

页码：11126 / 11127

页数：2

共 23 条

[1] Oxide surfaces as environmental interfaces [J].

Al-Abadleh, HA ;

Grassian, VH .

SURFACE SCIENCE REPORTS, 2003, 52 (3-4) :63-161

[2]

Atkins P., 2014, Physical chemistry

[3]

BERSHEVITZ O, 2004, J AM CHEM SOC, V126, P482

[4] Benzenecarboxylate surface complexation at the goethite (α-FeOOH)/water interface:: I.: A mechanistic description of pyromellitate surface complexes from the combined evidence of infrared spectroscopy, potentiometry, adsorption data, and surface complexation modeling [J].

Boily, JF ;

Nilsson, N ;

Persson, P ;

Sjöberg, S .

LANGMUIR, 2000, 16 (13) :5719-5729

[5] Surface science - How minerals react with water [J].

Brown, GE .

SCIENCE, 2001, 294 (5540) :67-+

[6] Metal oxide surfaces and their interactions with aqueous solutions and microbial organisms [J].

Brown, GE ;

Henrich, VE ;

Casey, WH ;

Clark, DL ;

Eggleston, C ;

Felmy, A ;

Goodman, DW ;

Grätzel, M ;

Maciel, G ;

McCarthy, MI ;

Nealson, KH ;

Sverjensky, DA ;

Toney, MF ;

Zachara, JM .

CHEMICAL REVIEWS, 1999, 99 (01) :77-174

[7] UV-vis spectroscopic determination of the dissociation constant of bichromate from 160 to 400 °C [J].

Chlistunoff, JB ;

Johnston, KP .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (20) :3993-4003

[8]

Finlayson-Pitts B. J., 2000, Chemistry of the Upper and Lower Atmosphere

[9] Modeling metal binding to soils:: The role of natural organic matter [J].

Gustafsson, JP ;

Pechová, P ;

Berggren, D .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2003, 37 (12) :2767-2774

[10]

Katz S.A., 1994, BIOL ENV CHEM CHROMI

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