Chemical, structural and magnetic studies of Mn0.50Ti2(PO4)3 and its solid solution with NaTi2(PO4)3

被引：19

作者：

Fakrane, H

Aatiq, A

Lamire, M

El Jazouli, A

Delmas, C

机构：

[1] LCS Fac Sci Ain Chock, Dept Chim, Chim Solide Lab, Casablanca, Morocco

[2] Fac Sci Ben MSik, Lab Chim Mat Solides, Casablanca, Morocco

[3] Univ Bordeaux 1, Lab Chim Mat Condensee Bordeaux, Bordeaux, France

来源：

ANNALES DE CHIMIE-SCIENCE DES MATERIAUX | 1998年 / 23卷 / 1-2期

关键词：

D O I：

10.1016/S0151-9107(98)80028-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Na(1-2x)MnxTi2(PO4)(3) (0 less than or equal to x less than or equal to 0.5) phosphates have been prepared by solid state reaction and by sol-gel method. The X-ray diffraction study shows that these materials belong to the Nasicon-type structure. The structure of Mn0.5Ti2(PO4)(3) has been solved in the <R(3)over bar> space group. Mn2+ ions are ordered in half of M(1) sites. The magnetic study undertaken on Mn0.5Ti2(PO4)(3) shows a paramagnetic behaviour with absence of Mn2+-Mn2+ interactions even at low temperature.

引用

页码：81 / 84

页数：4

共 9 条

[1] MG0.5TI2(PO4)3 - A NEW MEMBER OF THE NASICON FAMILY WITH LOW THERMAL-EXPANSION [J].