Introduction of several trifluoromethyl groups onto the activated aromatic materials with CF3TMS-CuI-KF system

被引：16

作者：

Kitazume, T ^{[1
]}

Nakajima, S ^{[1
]}

机构：

[1] Tokyo Inst Technol, Grad Sch Biosci & Biotechnol, Midori Ku, Yokohama, Kanagawa 2268501, Japan

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2004年 / 125卷 / 10期

关键词：

trifluoromethylation; decyanotrifluoromethylation; multitrifluoromethylation;

D O I：

10.1016/j.jfluchem.2004.04.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Trifluoromethylation onto the tetrafluorophthalonitrile and tetrafluoroisophthalonitrile has been carried out using CF3TMS-CuI-KF system, and it was demonstrated that these trifluoromethylation enabled us to successfully construct di- and/or tri-trifluoromethylated benzonitriles via the decyanotrifluoromethylation. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：1447 / 1449

页数：3

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