Crystal structures of copper(III) dithiocarbamate complexes [Cu(η2-S2CNMe2)2][ClO4] and [Cu(η2-S2CNEt2)2][FeCl4] with and without anion-cation interactions

被引：26

作者：

Hogarth, G ^{[1
]}

Pateman, A ^{[1
]}

Redmond, SP ^{[1
]}

机构：

[1] UCL, Dept Chem, London WC1H 0AJ, England

来源：

INORGANICA CHIMICA ACTA | 2000年 / 306卷 / 02期

关键词：

crystal structures; copper complexes; dithiocarbamate complexes;

D O I：

10.1016/S0020-1693(00)00172-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Copper(III) dithiocarbamate complexes [Cu(eta(2)-S2CNMe2)(2)][ClO4] and [Cu(eta(2)-S2CNEt2)(2)][FeCl4] have been characterised crystallographically. Both contain square-planar Cu(III) centres which attain an overall distorted octahedral coordination environment via long-range intermolecular interactions. In [Cu(eta(2)-S2CNEt2)(2)][FeCl4]. anions and cations do not interact and Cu(III) centres form an infinite chain held together by weak copper-sulfur interactions. In [Cu(eta(2)-S2CNMe2)(2)][ClO4], perchlorate anions interact weakly with the Cu(III) centre [Cu-O 2.753(3) Angstrom] which attains overall six coordination via a Cu-S interaction with a second copper-dithiocarbamate-perchlorate unit. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：232 / 236

页数：5

共 37 条

[1] COPPER(III) AND NICKEL(III) DIETHYLDITHIOCARBAMATES - AN EXAMPLE OF COPPER(II) DISPROPORTIONATION [J].