Template free, large scale synthesis of cobalt nanowires using magnetic fields for alignment

被引:64
作者
Athanassiou, E. K. [1 ]
Grossmann, P. [1 ]
Grass, R. N. [1 ]
Stark, W. J. [1 ]
机构
[1] ETH, Inst Chem & Bioengn, CH-8093 Zurich, Switzerland
关键词
D O I
10.1088/0957-4484/18/16/165606
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The application of an external magnetic field on a metallic cobalt nanoparticle loaded exhaust gas stream produced by reducing flame synthesis resulted in the formation of self-aligned metallic cobalt nanowires of 20-50 nm diameter. This template free, continuous and rapid production method afforded nanowires with an aspect ratio of over 1000 (length/diameter) at a production rate of over 30 g h(-1). At high magnetic fields the nanowires formed bundles with distinctive parallel orientation. In the absence of a directing magnetic field, thermophoresis promoted an irregular growth and resulted in highly branched and porous nanomeshes on cooled, stainless steel collectors. The high production rates of this template free preparation method suggest application of the process for large scale manufacturing of magnetic nanomeshes for filtration or nanowires for magnetic storage and anisotropic functional materials.
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页数:7
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共 60 条
[1]   MONTE-CARLO SIMULATION OF PARTICLE COAGULATION AND SINTERING [J].
AKHTAR, MK ;
LIPSCOMB, GG ;
PRATSINIS, SE .
AEROSOL SCIENCE AND TECHNOLOGY, 1994, 21 (01) :83-93
[2]   Large-scale production of carbon-coated copper nanoparticles for sensor applications [J].
Athanassiou, EK ;
Grass, RN ;
Stark, WJ .
NANOTECHNOLOGY, 2006, 17 (06) :1668-1673
[3]   Generation and growth mechanism of metal (Fe, Co, Ni) nanotube arrays [J].
Cao, Huaqiang ;
Wang, Liduo ;
Qiu, Yong ;
Wu, Qingzhi ;
Wang, Guozhi ;
Zhang, Lei ;
Liu, Xiangwen .
CHEMPHYSCHEM, 2006, 7 (07) :1500-1504
[4]   Effect of magnetic field on self-assembling of colloidal Co magnetic nanoparticles [J].
Chitu, L. ;
Chushkin, Y. ;
Luby, S. ;
Majkova, E. ;
Leo, G. ;
Satka, A. ;
Giersig, M. ;
Hilgendorff, M. .
APPLIED SURFACE SCIENCE, 2006, 252 (15) :5559-5562
[5]   Magnetization processes in nickel and cobalt electrodeposited nanowires [J].
Ferre, R ;
Ounadjela, K ;
George, JM ;
Piraux, L ;
Dubois, S .
PHYSICAL REVIEW B, 1997, 56 (21) :14066-14075
[6]   Approach to fabricating Co nanowire arrays with perpendicular anisotropy: Application of a magnetic field during deposition [J].
Ge, SH ;
Li, C ;
Ma, X ;
Li, W ;
Xi, L ;
Li, CX .
JOURNAL OF APPLIED PHYSICS, 2001, 90 (01) :509-511
[7]   Mesostructures of cobalt nanocrystals. 1. Experiment and theory [J].
Germain, V ;
Richardi, J ;
Ingert, A ;
Pileni, MP .
JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (12) :5541-5547
[8]   THERMOPHORESIS OF AEROSOL-PARTICLES IN LAMINAR BOUNDARY-LAYER ON A FLAT-PLATE [J].
GOREN, SL .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1977, 61 (01) :77-85
[9]   ULTRAFINE METAL PARTICLES [J].
GRANQVIST, CG ;
BUHRMAN, RA .
JOURNAL OF APPLIED PHYSICS, 1976, 47 (05) :2200-2219
[10]   Grain growth resistance and increased hardness of bulk nanocrystalline fcc cobalt prepared by a bottom-up approach [J].
Grass, R. N. ;
Dietiker, M. ;
Solenthaler, C. ;
Spolenak, R. ;
Stark, W. J. .
NANOTECHNOLOGY, 2007, 18 (03)