The molecular structure of (PSH+)(nido-7,8-C2B9H12-) determined by neutron diffraction (PS = proton sponge, 1,8-bis(dimethylamino)naphthalene)

被引：40

作者：

Fox, MA

Goeta, AE

Howard, JAK

Hughes, AK

Johnson, AL

Keen, DA

Wade, K

Wilson, CC

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Rutherford Appleton Lab, CLRC, ISIS, Didcot OX11 0QX, Oxon, England

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 01期

关键词：

D O I：

10.1021/ic000961e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A neutron diffraction study of the salt (PSH+)(nido-7 8-C2B9H12-) reveals the unsymmetrically bridging site of the endo hydrogen in the carborane anion. This is the first neutron diffraction structure determination of a cluster borane or carborane containing natural abundance boron isotopes.

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页码：173 / +

页数：4

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