High activity ethylene polymerisation catalysts based on chelating diamide ligands

被引：104

作者：

Gibson, VC

Kimberley, BS

White, AJP

Williams, DJ

Howard, P

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AY, England

[2] BP Chem, Sunbury Res Ctr, Sunbury On Thames TW16 7LN, Middx, England

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 03期

关键词：

D O I：

10.1039/a706304k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of Zr(NMe2)(4) with RNH(SiPh2)NHR and RNH(Me2SiCH2CH2SiMe2)NHR (R = 2,6-Me2C6H3) affords the four-and seven-membered chelate complexes {Zr[RN(SiPh2,)NR](NMe2)(2)(HNMe2)} and {Zr[RN(Me2SiCH2CH2SiMe2)NR](NMe2)(2)} respectively; a dramatic effect of chelate ring size on ethylene polymerisation activity and kinetic profile is found.

引用

页码：313 / 314

页数：2

共 13 条

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