Infrared (ATR) study of hydrogen bonding in solutions containing water and ethylene carbonate

被引：38

作者：

Brooksby, PA ^{[1
]}

Fawcett, WR ^{[1
]}

机构：

[1] Univ Calif Davis, Dept Chem, Davis, CA 95616 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2000年 / 104卷 / 35期

关键词：

D O I：

10.1021/jp000551b

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The structure and hydrogen bonding of water in solutions containing EC at different concentrations were examined using infrared (ATR) spectroscopy. Analysis of the OH stretch vibrations of water was' performed using several different techniques, and the results were compared to similar analyses found in the Literature. Factor analysis and curve fitting show two concentration-dependent regions wherein the structure of water in the mixture is critically disrupted and hydrogen bonding is significantly changed.

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页码：8307 / 8314

页数：8

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