Deposition of oriented SrSO4 coatings by electrogeneration of acid

被引:13
作者
Dinamani, M
Kamath, PV [1 ]
Seshadri, R
机构
[1] Bangalore Univ, Cent Coll, Dept Chem, Bangalore 560001, Karnataka, India
[2] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India
[3] Univ Calif Santa Barbara, Dept Mat, Santa Barbara, CA 93106 USA
关键词
strontium sulfate; electrochemical synthesis; orientated crystallization; crystal morphology;
D O I
10.1016/S1293-2558(03)00085-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
We report the use of electrogeneration of acid to electrochemically precipitate crystalline strontium sulfate coatings from EDTA stabilized solutions onto stainless steel anodes. This is the first report of the electrodeposition of strontium sulfate. A study of the deposited SrSO4 by microscopy and diffraction suggests that by changing conditions of current and time, control over crystallite habit and crystallite orientation with respect to the substrate can be achieved. (C) 2003 editions scientifiques et medicales Elsevier SAS. All rights reserved.
引用
收藏
页码:805 / 810
页数:6
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