The first polyoxoalkoxovanadium germanate anion with a novel cage-like structure: solvothermal synthesis and characterization

被引：38

作者：

Chen, YM

Wang, EB ^{[1
]}

Lin, BZ

Wang, ST

机构：

[1] NE Normal Univ, Fac Chem, Inst Polyoxometalate Chem, Changchun 130024, Peoples R China

[2] Quanzhou Normal Coll, Fac Chem, Quanzhou 362000, Peoples R China

[3] Huaqiao Univ, Inst Mat Phys Chem, Quanzhou 362011, Peoples R China

来源：

DALTON TRANSACTIONS | 2003年 / 04期

关键词：

D O I：

10.1039/b208489a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The first example of polyoxoalkoxovanadium germanate, (NH4)(2)[H2V9Ge6O26(L)(6)].0.65H(2)O (H2L = HOCH2CH2OH), was solvothermally synthesized, and its polyanion is made up of six VO6 octahedra, three VO5 square pyramids and six GeO4 tetrahedra with six bridging ethylene glycol ligands projecting outwards from the central core.

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页码：519 / 520

页数：2

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