The 5d level positions of the trivalent lanthanides in inorganic compounds

被引:559
作者
Dorenbos, P [1 ]
机构
[1] Delft Univ Technol, Inst Interfac Reactor, Radiat Technol Grp, NL-2629 JB Delft, Netherlands
关键词
trivalent lanthanides; 5d-levels; Stokes shift; crystal field depression;
D O I
10.1016/S0022-2313(00)00229-5
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The literature on 4f(n) <-> 4f(n-1)5d transitions of the trivalent lanthanides in inorganic compounds has been collected. From critically analyzing fd-excitation, absorption, reflection and df-emission spectra, values for the spectroscopic red shift of 5d levels and the stokes shift were determined. Data pertaining to 368 different lanthanide sites in over 300 different compounds (fluorides, chlorides, bromide, iodides, oxides, sulfides, selenides and oxy-nitrides) has been compiled. From the data, it is possible to predict for each of the 12 lanthanide ions (Ce3+, Pr3+ until Yb3+) doped in any of the compounds compiled, the position of the lowest 5d levels with typically +/-600 cm(-1) accuracy. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:155 / 176
页数:22
相关论文
共 241 条
  • [1] Abdulsabirov R. Yu., 1987, Soviet Physics - Crystallography, V32, P559
  • [2] FLUORESCENCE OF MN-2+ IN CACO3
    AGUILAR, GM
    OSENDI, MI
    [J]. JOURNAL OF LUMINESCENCE, 1982, 27 (04) : 365 - 375
  • [3] [Anonymous], 1969, MATER RES BULL
  • [4] Antonyak O. T., 1986, Optics and Spectroscopy, V60, P743
  • [5] Antonyak OT, 1998, OPT SPECTROSC+, V84, P861
  • [6] LUMINESCENCE PROPERTIES OF PR3+ IN MONOCLINIC GADOLINIUM SESQUIOXIDE
    ARAI, M
    MATSUDA, N
    TAMATANI, M
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1993, 192 (1-2) : 45 - 47
  • [7] LUMINESCENCE AND VIBRATIONAL STRUCTURE OF THE LUMINOPHORS CAS-CE3+ AND CASE-CE3+
    ASANO, S
    YAMASHITA, N
    OGAWA, Y
    [J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1983, 118 (01): : 89 - 100
  • [8] LUMINESCENCE OF CE3+ ION IN THE LUMINOPHOR MGS
    ASANO, S
    YAMASHITA, N
    OHNISHI, T
    [J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1980, 99 (02): : 661 - 672
  • [9] SENSITIZATION OF LUMINESCENCE OF CASO4-DY
    ATONE, MS
    DHOBLE, SJ
    MOHARIL, SV
    DHOPTE, SM
    MUTHAL, PL
    KONDAWAR, VK
    [J]. PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1993, 135 (01): : 299 - 305
  • [10] IMPACT OF ION-HOST INTERACTIONS ON THE 5D-TO-4F SPECTRA OF LANTHANIDE RARE-EARTH-METAL IONS .2. THE CE-DOPED ELPASOLITES
    AULL, BF
    JENSSEN, HP
    [J]. PHYSICAL REVIEW B, 1986, 34 (10): : 6647 - 6655