A potential low-temperature oxide-ion conductor:: La2-xBaxMo2O9

被引:48
作者
Basu, S [1 ]
Devi, PS [1 ]
Maiti, HS [1 ]
机构
[1] Cent Glass & Ceram Res Inst, Electroceram Div, Kolkata 700032, India
关键词
D O I
10.1063/1.1808505
中图分类号
O59 [应用物理学];
学科分类号
摘要
An oxide ion conducting material, La1.94Ba0.06Mo2O9, with ionic conductivity of the order of 0.084 S/cm at 800 degreesC in air was prepared by a citrate-nitrate auto-ignition process. A 3% Ba doping has suppressed the resistive transition of unsubstituted La2Mo2O9, which in turn stabilized the high-temperature cubic phase at room temperature as confirmed from x-ray diffraction, differential thermal analysis, and dilatometric studies. Impedance measurements on sintered La1.94Ba0.06Mo2O9 further lend strong support that a small amount of Ba doping has increased the overall conductivity of the parent compound La2Mo2O9 to a notable extent both at low and high temperatures. (C) 2004 American Institute of Physics.
引用
收藏
页码:3486 / 3488
页数:3
相关论文
共 14 条
[1]   Synthesis and characterization of the anionic conductor system La2Mo2O9-0.5xFx (x=0.02-0.30) [J].
Arulraj, A ;
Goutenoire, F ;
Tabellout, M ;
Bohnke, O ;
Lacorre, P .
CHEMISTRY OF MATERIALS, 2002, 14 (06) :2492-2498
[2]   Structural and electrochemical features of fast oxide ion conductors [J].
Boivin, JC .
INTERNATIONAL JOURNAL OF INORGANIC MATERIALS, 2001, 3 (08) :1261-1266
[3]   Recent material developments in fast oxide ion conductors [J].
Boivin, JC ;
Mairesse, G .
CHEMISTRY OF MATERIALS, 1998, 10 (10) :2870-2888
[4]   Synthesis, structures, and thermal expansion of the La2W2-xMoxO9 series [J].
Collado, JA ;
Aranda, MAG ;
Cabeza, A ;
Olivera-Pastor, P ;
Bruque, S .
JOURNAL OF SOLID STATE CHEMISTRY, 2002, 167 (01) :80-85
[5]   Synthesis and characterization of IT-electrolyte with perovskite structure La0.8Sr0.2Ga0.85Mg0.15O3-δ by glycine-nitrate combustion method [J].
Cong, LG ;
He, TM ;
Ji, YA ;
Guan, PF ;
Huang, YL ;
Su, WH .
JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 348 (1-2) :325-331
[6]  
DEVI PS, 1994, J SOLID STATE CHEM, V109, P3542
[7]   Thermal, structural and transport properties of the fast oxide-ion conductors La2-xRxMo2O9 (R=Nd, Gd, Y) [J].
Georges, S ;
Goutenoire, F ;
Altorfer, F ;
Sheptyakov, D ;
Fauth, F ;
Suard, E ;
Lacorre, P .
SOLID STATE IONICS, 2003, 161 (3-4) :231-241
[8]   Reducibility of fast oxide-ion conductors La2-xRxMo2-yWyO9 (R = Nd, Gd) [J].
Georges, S ;
Goutenoire, F ;
Laligant, Y ;
Lacorre, P .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (09) :2317-2321
[9]   Ceramic technology - Oxide-ion conductors by design [J].
Goodenough, JB .
NATURE, 2000, 404 (6780) :821-823
[10]   Crystal structure of La2Mo2O9, a new fast oxide-ion conductor [J].
Goutenoire, F ;
Isnard, O ;
Retoux, R ;
Lacorre, P .
CHEMISTRY OF MATERIALS, 2000, 12 (09) :2575-2580