Adsorption of NO and CO on silver-exchanged microporous materials

被引：25

作者：

Akolekar, DB ^{[1
]}

Bhargava, SK ^{[1
]}

机构：

[1] RMIT Univ, Dept Appl Chem, Melbourne, Vic 3001, Australia

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2000年 / 157卷 / 1-2期

关键词：

FTIR; nitric oxide; carbon monoxide; CO-Ag complexes; NO-Ag complexes; Ag-SAPO-34; Ag-ZSM-5; BET; Ag sites;

D O I：

10.1016/S1381-1169(00)00055-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Investigations of nitric bride (NO) and carbon monoxide (CO) adsorption were carried out on the silver-exchanged high silica pentasil zeolite and chabazite-type silico-aluminophosphate materials. Novel Ag-SAPO-34 and Ag-ZSM-5 catalysts were prepared and characterised using routine instrumental techniques. Detailed FTIR studies were carried out on the interaction of NO/CO over Ag-SAPO-34 and Ag-ZSM-5. FTIR spectra indicated the formation of various NO/CO complexes on the silver-exchanged materials. Influence of the NO/CO pressure and evacuation on the surface species have been studied. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：199 / 206

页数：8

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