A Nonfullerene Small Molecule Acceptor with 3D Interlocking Geometry Enabling Efficient Organic Solar Cells

被引:212
作者
Lee, Jaewon [1 ]
Singh, Ranbir [1 ]
Sin, Dong Hun [1 ]
Kim, Heung Gyu [1 ]
Song, Kyu Chan [1 ]
Cho, Kilwon [1 ]
机构
[1] Pohang Univ Sci & Technol, Dept Chem Engn, Pohang 790784, South Korea
关键词
ELECTRON-ACCEPTORS; CHARGE GENERATION; FULLERENE; DONOR; PERFORMANCE; AGGREGATION; COPOLYMER; MOBILITY;
D O I
10.1002/adma.201504010
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new 3D nonfullerene small-molecule acceptor is reported. The 3D interlocking geometry of the small-molecule acceptor enables uniform molecular conformation and strong intermolecular connectivity, facilitating favorable nanoscale phase separation and electron charge transfer. By employing both a novel polymer donor and a nonfullerene small-molecule acceptor in the solution-processed organic solar cells, a high-power conversion efficiency of close to 6% is demonstrated.
引用
收藏
页码:69 / +
页数:9
相关论文
共 61 条
[1]   Small-Molecule, Nonfullerene Acceptors for Polymer Bulk Heterojunction Organic Photovoltaics [J].
Anthony, John E. .
CHEMISTRY OF MATERIALS, 2011, 23 (03) :583-590
[2]   Materials and Applications for Large Area Electronics: Solution-Based Approaches [J].
Arias, Ana Claudia ;
MacKenzie, J. Devin ;
McCulloch, Iain ;
Rivnay, Jonathan ;
Salleo, Alberto .
CHEMICAL REVIEWS, 2010, 110 (01) :3-24
[3]   Comparing the Device Physics and Morphology of Polymer Solar Cells Employing Fullerenes and Non-Fullerene Acceptors [J].
Bloking, Jason T. ;
Giovenzana, Tommaso ;
Higgs, Andrew T. ;
Ponec, Andrew J. ;
Hoke, Eric T. ;
Vandewal, Koen ;
Ko, Sangwon ;
Bao, Zhenan ;
Sellinger, Alan ;
McGehee, Michael D. .
ADVANCED ENERGY MATERIALS, 2014, 4 (12)
[4]   High Performance Organic Solar Cells Based on a Twisted Bay-Substituted Tetraphenyl Functionalized Perylenediimide Electron Acceptor [J].
Cai, Yunhao ;
Huo, Lijun ;
Sun, Xiaobo ;
Wei, Donghui ;
Tang, Mingsheng ;
Sun, Yanming .
ADVANCED ENERGY MATERIALS, 2015, 5 (11)
[5]   Ultralong nanobelts self-assembled from an asymmetric perylene tetracarboxylic diimide [J].
Che, Yanke ;
Datar, Aniket ;
Balakrishnan, Kaushik ;
Zang, Ling .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (23) :7234-+
[6]   A perylene diimide (PDI)-based small molecule with tetrahedral configuration as a non-fullerene acceptor for organic solar cells [J].
Chen, Wangqiao ;
Yang, Xuan ;
Long, Guankui ;
Wan, Xiangjian ;
Chen, Yongsheng ;
Zhang, Qichun .
JOURNAL OF MATERIALS CHEMISTRY C, 2015, 3 (18) :4698-4705
[7]   Morphology characterization in organic and hybrid solar cells [J].
Chen, Wei ;
Nikiforov, Maxim P. ;
Darling, Seth B. .
ENERGY & ENVIRONMENTAL SCIENCE, 2012, 5 (08) :8045-8074
[8]   Low Band-Gap Conjugated Polymers with Strong Interchain Aggregation and Very High Hole Mobility Towards Highly Effi cient Thick- Film Polymer Solar Cells [J].
Chen, Zhenhui ;
Cai, Ping ;
Chen, Junwu ;
Liu, Xuncheng ;
Zhang, Lianjie ;
Lan, Linfeng ;
Peng, Junbiao ;
Ma, Yuguang ;
Cao, Yong .
ADVANCED MATERIALS, 2014, 26 (16) :2586-2591
[9]   The case for organic photovoltaics [J].
Darling, Seth B. ;
You, Fengqi .
RSC ADVANCES, 2013, 3 (39) :17633-17648
[10]   Polymer-Fullerene Bulk-Heterojunction Solar Cells [J].
Dennler, Gilles ;
Scharber, Markus C. ;
Brabec, Christoph J. .
ADVANCED MATERIALS, 2009, 21 (13) :1323-1338