Determination of an acidic scale in room temperature ionic liquids

被引：397

作者：

Thornazeau, C

Olivier-Bourbigou, H

Magna, L

Luts, S

Gilbert, B

机构：

[1] Inst Francais Petr, F-92852 Rueil Malmaison, France

[2] Univ Liege, B-4000 Liege, Belgium

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 18期

关键词：

D O I：

10.1021/ja0297382

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The acidity scale of different Brønsted acids in ionic liquids such as [BMIM][NTf2], [BMIM][BF4], and [BMMIM][BF4] has been investigated by determination of Hammett functions, using a spectrophotometric indicator method. This scale should permit one to correlate the acidity strength of ionic liquid systems with their ability to achieve acid-catalyzed reactions. Copyright © 2003 American Chemical Society.

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页码：5264 / 5265

页数：2

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